Multiphase equilibria of waxy systems with predictive equations of state and a solid solution model

Nasrifar, K. and Moshfeghian, M. (2012) Multiphase equilibria of waxy systems with predictive equations of state and a solid solution model. Fluid Phase Equilibria, 314. pp. 60-68. ISSN 03783812

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Abstract

A thermodynamic model is developed to predict the vapor-liquid, solid-liquid, solid-vapor and solid-liquid-vapor equilibria of systems containing methane with waxy components. The model takes the advantages of equations of state to describe the vapor and liquid phases. The solid phase is described by Coutinho's activity coefficient model, i.e., the solid phase is assumed to be orthorhombic solid solution. Impact of pressure on the solid phase is included by coupling solid-liquid Clapeyron relationship with Poynting correction factor. While no adjustable parameter is used, the model satisfactorily predicts the phase boundaries of the synthetic and real systems resembling gas condensate mixtures for wide ranges of pressure and temperature. © 2011 Elsevier B.V.

Item Type: Article
Additional Information: cited By 12
Uncontrolled Keywords: Activity coefficient model; Adjustable parameters; Correction factors; Equation of state; Equilibrium calculations; Gas condensate mixture; High pressure; Liquid phasis; Multiphase equilibria; Predictive equations; Pressure and temperature; Real systems; Solid-liquid; Solid-liquid-vapor equilibria; Solid-phase; Solid-vapor; Thermodynamic model; Vapor-liquid, Equations of state of liquids; Gas condensates; Liquids; Methane; Phase boundaries; Vapors; Waxes, Solid solutions
Depositing User: Mr Ahmad Suhairi UTP
Date Deposited: 09 Nov 2023 15:51
Last Modified: 09 Nov 2023 15:51
URI: https://khub.utp.edu.my/scholars/id/eprint/3097

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