TY  - JOUR
TI  - Effect of Cation Modification on the Physicochemical Properties and CO2 Solubility: Nonfluorinated Phosphonium-Based Ionic Liquids Incorporating a Dioctylsulfosuccinate Anion
SP  - 3672
N1  - cited By 5
AV  - none
EP  - 3683
SN  - 00219568
PB  - American Chemical Society
KW  - Ionic liquids; Positive ions; Refractive index; Solubility
KW  -  Cation modification; Dicationic ionic liquids; Henry's Law constant; Phosphonium-based ionic liquids; Physicochemical property; Physio-chemical properties; Thermodynamic functions; Trihexyltetradecylphosphonium
KW  -  Carbon dioxide
ID  - scholars9880
N2  - In the current work, a series of phosphonium-based monocationic and dicationic ionic liquids (trihexyltetradecylphosphonium dioctylsulfosuccinate, P6,6,6,14DOSS; trioctyltetradecylphosphonium dioctylsulfosuccinate, P8,8,8,14DOSS; 1,6-bis(trioctylphosphonium)hexane dioctylsulfosuccinate, P8,8,8C6P8,8,8 DOSS2; and 1,10-bis(trioctylphosphonium)decane dioctylsulfosuccinate, P8,8,8C10P8,8,8DOSS2) were prepared, and their characterization was done using NMR and elemental analysis. Their physiochemical properties (thermal stability, viscosity, density, and refractive index) and CO2 solubility (at pressures 1, 5, 10, 15, and 20 bar) were investigated. The cation and alkyl chain effects on the properties and CO2 capturing efficiency were discussed. The thermodynamic functions of solvation were calculated using the variation of Henry's law constants with temperature. © 2018 American Chemical Society.
IS  - 10
VL  - 63
UR  - https://www.scopus.com/inward/record.uri?eid=2-s2.0-85053336287&doi=10.1021%2facs.jced.8b00109&partnerID=40&md5=40fb59ad40a63647736ecfaff8cb7388
A1  - Ziyada, A.K.
A1  - Wilfred, C.D.
JF  - Journal of Chemical and Engineering Data
Y1  - 2018///
ER  -