eprintid: 9876 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/00/98/76 datestamp: 2023-11-09 16:36:31 lastmod: 2023-11-09 16:36:31 status_changed: 2023-11-09 16:30:02 type: article metadata_visibility: show creators_name: Siyal, A.A. creators_name: Shamsuddin, M.R. creators_name: Khan, M.I. creators_name: Rabat, N.E. creators_name: Zulfiqar, M. creators_name: Man, Z. creators_name: Siame, J. creators_name: Azizli, K.A. title: A review on geopolymers as emerging materials for the adsorption of heavy metals and dyes ispublished: pub keywords: adsorbent; ammonia; arsenic; cadmium; calcium; cesium; chromium; cobalt; congo red; copper; crystal violet; direct blue 15; direct sky blue 5 B; dye; geopolymer; heavy metal; lead; magnesium; methyl orange; methyl violet; methylene blue; nickel; phosphorus; polymer; reagent; sulfate; unclassified drug; zinc; coloring agent; heavy metal, adsorption; cost analysis; dye; heavy metal; perforation; pollutant removal; polymer; research work; wastewater; wastewater treatment; water resource, adsorption kinetics; biogeochemistry; chemical structure; entropy; fecal coliform; Fourier transform infrared spectroscopy; isotherm; Langmuir isotherm; polymerization; Review; slag; structure analysis; surface area; surface property; thermodynamics; waste component removal; waste water; waste water management; water pollutant; water pollution; X ray diffraction; adsorption; chemistry; isolation and purification; kinetics; water pollutant, Adsorption; Coloring Agents; Kinetics; Metals, Heavy; Waste Water; Water Pollutants, Chemical note: cited By 297 abstract: The world water resources are contaminated due to discharge of a large number of pollutants from industrial and domestic sources. A variety of a single and multiple units of physical, chemical, and biological processes are employed for pollutants removal from wastewater. Adsorption is the most widely utilized process due to high efficiency, simple procedure and cost effectiveness. This paper reviews the research work carried out on the use of geopolymer materials for the adsorption of heavy metals and dyes. Geopolymers possess good surface properties, heterogeneous microstructure and amorphous structure. The performance of geopolymers in the removal of heavy metals and dyes is reported comparable to other materials. The pseudo-second order kinetics and Langmuir isotherm models mostly fit to the adsorption data suggesting homogeneous distribution of adsorption sites with the formation of monolayer adsorbate on the surface of geopolymers. Adsorption of heavy metals and dyes onto geopolymers is spontaneous, endothermic and entropy driven process. Future research should focus on the enhancement of geopolymer performance, testing on pollutants other than heavy metals and dyes, and verification on real wastewater in continuous operation. © 2018 Elsevier Ltd date: 2018 publisher: Academic Press official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85052861279&doi=10.1016%2fj.jenvman.2018.07.046&partnerID=40&md5=244d933ae31e72cded35eccb6ffe30e5 id_number: 10.1016/j.jenvman.2018.07.046 full_text_status: none publication: Journal of Environmental Management volume: 224 pagerange: 327-339 refereed: TRUE issn: 03014797 citation: Siyal, A.A. and Shamsuddin, M.R. and Khan, M.I. and Rabat, N.E. and Zulfiqar, M. and Man, Z. and Siame, J. and Azizli, K.A. (2018) A review on geopolymers as emerging materials for the adsorption of heavy metals and dyes. Journal of Environmental Management, 224. pp. 327-339. ISSN 03014797