eprintid: 9618
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/96/18
datestamp: 2023-11-09 16:36:16
lastmod: 2023-11-09 16:36:16
status_changed: 2023-11-09 16:29:25
type: conference_item
metadata_visibility: show
creators_name: Alva, S.
creators_name: Sundari, R.
creators_name: A Aziz, A.S.
creators_name: A Rashid, N.A.
creators_name: Gunawan, W.
title: Development of Ammonium-Selective Electrode Based on PVC/MB28 Membrane
ispublished: pub
keywords: Chlorine compounds, Ammonium ions; Butyl acrylates; Dioctyl sebacate; Hybrid membrane; ISE-NH4+; MB28; Plasticized materials; Selective electrodes, Polyvinyl chlorides
note: cited By 3; Conference of 1st International Conference on Design, Engineering and Computer Sciences 2018, ICDECS 2018 ; Conference Date: 9 August 2018; Conference Code:142681
abstract: In this study, the ISE-NH4 + sensor based on hybrid membrane of the poly (vinyl chloride)/methyl methacrylate-butyl acrylate 2:8 co-polymer (PVC/MB28) has been successfully developed, where the ratio between PVC: MB28 is 9:1. Meanwhile, the plasticized material used is dioctyl sebacate (DOS) of 66.34 wt. , the amount of lipophilic salt of the potassium tetrakis (4-chlorophenyl) borate (KTpClPB) used is 0.99 wt. , and nonactine as much as 2.97 wt.. The addition of the MB28 co-polymer has successfully improved the performance and mechanical strength of ISE-NH4+ especially at measurements at 40°C. The ISE-NH4 + sensor based on PVC/MB28 has a Nernstian number of 55.4 and 58.7 mV/dec for measurement at 25°C and 40°C with the linear range between 0.1 - 10-5 M. While the ISE-NH4+ sensors based on PVC used as benchmarking have Nernstian numbers of 54.2 and 35.3 mV/dec for measurements at 25 ° C and 40 ° C, where the linear range is 0.1 - 10-5 M and 0.1 - 10-3 M. The addition of MB28 also does not cause the selectivity of the ISE-NH4 + sensor to decrease, where the result of the selectivity between PVC/MB28 is comparable to PVC. © Published under licence by IOP Publishing Ltd.
date: 2018
publisher: Institute of Physics Publishing
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85058048623&doi=10.1088%2f1757-899X%2f453%2f1%2f012042&partnerID=40&md5=1f7c40119317d139d1d99765b0737dcc
id_number: 10.1088/1757-899X/453/1/012042
full_text_status: none
publication: IOP Conference Series: Materials Science and Engineering
volume: 453
number: 1
refereed: TRUE
issn: 17578981
citation:   Alva, S. and Sundari, R. and A Aziz, A.S. and A Rashid, N.A. and Gunawan, W.  (2018) Development of Ammonium-Selective Electrode Based on PVC/MB28 Membrane.  In: UNSPECIFIED.