eprintid: 9356
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/93/56
datestamp: 2023-11-09 16:21:20
lastmod: 2023-11-09 16:21:20
status_changed: 2023-11-09 16:14:55
type: article
metadata_visibility: show
creators_name: Tasfy, S.
creators_name: Mohd Zabidi, N.A.
creators_name: Shaharun, M.S.
creators_name: Subbarao, D.
title: Methanol production via CO2 hydrogenation reaction: Effect of catalyst support
ispublished: pub
keywords: Alumina; Aluminum oxide; Carbon dioxide; Catalyst activity; Catalyst selectivity; Copper oxides; Field emission microscopes; High resolution transmission electron microscopy; Hydrogenation; Methanol; Nanocatalysts; Nanoparticles; Physicochemical properties; Scanning electron microscopy; Supports; Temperature programmed desorption; Zinc compounds; Zirconia, Al2O3; Catalyst nano particles; Cu/ZnO catalyst; CuO nanoparticles; Field emission scanning electron microscopy; Fixed bed micro-reactor; Product selectivities; SBA-15, Catalyst supports
note: cited By 9
abstract: In this project, Cu-based catalyst was synthesised via impregnation method on various supports such as Al2O3, Al2O3-ZrO2, SBA-15 and Al-modified SBA-15. Samples were characterised by N2 adsorption-desorption, field-emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HRTEM), temperature-programmed desorption/reduction (TPD/R) and pulse chemisorption. The activity of the supported Cu-based catalyst was evaluated in a fixed-bed micro-reactor at 483 K, 2.25 MPa, and H2/CO2 ratio of 3:1. Our results showed that the nature of the oxide support influenced the physicochemical properties of the catalysts as well as the catalytic activity and product selectivity. The size of catalyst nanoparticles ranged from 9 nm to 37 nm, depending on the type of support used. The Cu-based catalyst supported on SBA-15 resulted in 13.96 CO2 conversion and methanol selectivity of 91.32 and these values were higher than those obtained using Cu-based catalyst supported on other oxide carriers. Copyright © 2017 Inderscience Enterprises Ltd.
date: 2017
publisher: Inderscience Publishers
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85014081962&doi=10.1504%2fIJNT.2017.082461&partnerID=40&md5=eb8e5e6532e0f7c6ded954f9c8290f45
id_number: 10.1504/IJNT.2017.082461
full_text_status: none
publication: International Journal of Nanotechnology
volume: 14
number: 1-6
pagerange: 410-421
refereed: TRUE
issn: 14757435
citation:   Tasfy, S. and Mohd Zabidi, N.A. and Shaharun, M.S. and Subbarao, D.  (2017) Methanol production via CO2 hydrogenation reaction: Effect of catalyst support.  International Journal of Nanotechnology, 14 (1-6).  pp. 410-421.  ISSN 14757435