eprintid: 9220 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/00/92/20 datestamp: 2023-11-09 16:21:11 lastmod: 2023-11-09 16:21:11 status_changed: 2023-11-09 16:14:33 type: article metadata_visibility: show creators_name: Norlaili, A. creators_name: Faiz, A. creators_name: Hazwan, A.H. creators_name: Fatima, G. creators_name: Megat, P.S.M.Y. creators_name: Aziz, H. creators_name: Rafiq, A. title: Synergistic effects of titanium dioxide and zinc borate on thermal degradation and water resistance of epoxy based intumescent fire retardant coatings ispublished: pub keywords: Corrosion resistance; Flame resistance; Image enhancement; Manufacture; Oxides; Polypropylenes; Scanning electron microscopy; Seawater corrosion; Thermogravimetric analysis; Titanium dioxide; Titanium oxides; Zinc coatings; Zinc compounds, Ammonium polyphosphates; Field emission scanning electron microscopes; Fire performance; Intumescent fire retardant coatings; Intumescent flame retardant; Titanium dioxides (TiO2); Water immersion tests; Zinc borate, Corrosion resistant coatings note: cited By 11; Conference of 2nd International Conference on Mechanical, Manufacturing and Process Plant Engineering, ICMMPE 2016 ; Conference Date: 23 November 2016 Through 24 November 2016; Conference Code:195589 abstract: This studies discuss the synergistic effects of titanium dioxide (TiO2) and zinc borate on thermal stability and water resistance of intumescent fire retardant coatings. TiO2 in association with a traditional intumescent flame retardant system which contains ammonium polyphosphate/expandable graphite/melamine/ zinc borate (APP-EG-MEL-ZB) was introduced to epoxy based coatings to improve the fire resistance. The influences of TiO2 on the properties of the coatings were investigated in detail by using Bunsen burner fire test, thermogravimetric analysis (TGA), field emission scanning electron microscope (FESEM) and water immersion test. Bunsen burner test revealed that incorporation of titanium dioxide in intumescent formulation reduced the steel substrate temperature from 240 °C to 116 °C. The TGA results proved that addition of TiO2 could enhance the anti-oxidation of the char layers and increase the residue weights of the coatings. The FESEM images demonstrated that addition of TiO2 could improve the foam structure of the char residue. Sea water resistance test demonstrated that the optimum mass age of TiO2 (6) exhibited great synergism with natural anti-corrosion agent, zinc borate, and improved corrosion resistance performance of intumescent coating formulations. © 2017 Trans Tech Publications, Switzerland. date: 2017 publisher: Trans Tech Publications Ltd official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85027079928&doi=10.4028%2fwww.scientific.net%2fKEM.740.41&partnerID=40&md5=fb23023445125e6bc31d3d2521b065ec id_number: 10.4028/www.scientific.net/KEM.740.41 full_text_status: none publication: Key Engineering Materials volume: 740 KE pagerange: 41-47 refereed: TRUE isbn: 9783035711202 issn: 10139826 citation: Norlaili, A. and Faiz, A. and Hazwan, A.H. and Fatima, G. and Megat, P.S.M.Y. and Aziz, H. and Rafiq, A. (2017) Synergistic effects of titanium dioxide and zinc borate on thermal degradation and water resistance of epoxy based intumescent fire retardant coatings. Key Engineering Materials, 740 KE. pp. 41-47. ISSN 10139826