eprintid: 8838 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/00/88/38 datestamp: 2023-11-09 16:20:46 lastmod: 2023-11-09 16:20:46 status_changed: 2023-11-09 16:13:39 type: article metadata_visibility: show creators_name: Dasan, Y.K. creators_name: Bhat, A.H. creators_name: Ahmad, F. title: Polymer blend of PLA/PHBV based bionanocomposites reinforced with nanocrystalline cellulose for potential application as packaging material ispublished: pub keywords: Cellulose derivatives; Mechanical permeability; Morphology; Nanocrystalline materials; Nanocrystals; Packaging materials; Palm oil; Polymer blends; Reinforcement, Bionanocomposites; Flexural; Mechanical and barriers; Nanocrystalline cellulose; Poly(3-hydroxybutyrate-co-3-hydroxyvalerate); Solution casting; Solvent casting method; TEMPO-mediated oxidation, Cellulose, Cellulose Derivatives; Lactic Acid; Mechanical Properties; Oxidation; Packaging; Permeability, cellulose; nanocomposite; nanoparticle; poly(3-hydroxybutyrate)-co-(3-hydroxyvalerate); polyester; polylactide, chemistry; packaging, Cellulose; Nanocomposites; Nanoparticles; Polyesters; Product Packaging note: cited By 86 abstract: The current research discusses the development of poly (lactic acid) (PLA) and poly-(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) reinforced nanocrystalline cellulose bionanocomposites. The nanocrystalline cellulose was derived from waste oil palm empty fruit bunch fiber by acid hydrolysis process. The resulting nanocrystalline cellulose suspension was then surface functionalized by TEMPO-mediated oxidation and solvent exchange process. Furthermore, the PLA/PHBV/nanocrystalline cellulose bionanocomposites were produced by solvent casting method. The effect of the addition of nanocrystalline cellulose on structural, morphology, mechanical and barrier properties of bionanocomposites was investigated. The results revealed that the developed bionanocomposites showed improved mechanical properties and decrease in oxygen permeability rate. Therefore, the developed bio-based composite incorporated with an optimal composition of nanocrystalline cellulose exhibits properties as compared to the polymer blend. © 2016 Elsevier Ltd date: 2017 publisher: Elsevier Ltd official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85006025119&doi=10.1016%2fj.carbpol.2016.11.012&partnerID=40&md5=9b7ba116350a3706e05df0cbcc1968a1 id_number: 10.1016/j.carbpol.2016.11.012 full_text_status: none publication: Carbohydrate Polymers volume: 157 pagerange: 1323-1332 refereed: TRUE issn: 01448617 citation: Dasan, Y.K. and Bhat, A.H. and Ahmad, F. (2017) Polymer blend of PLA/PHBV based bionanocomposites reinforced with nanocrystalline cellulose for potential application as packaging material. Carbohydrate Polymers, 157. pp. 1323-1332. ISSN 01448617