eprintid: 8804
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/88/04
datestamp: 2023-11-09 16:20:43
lastmod: 2023-11-09 16:20:43
status_changed: 2023-11-09 16:13:34
type: article
metadata_visibility: show
creators_name: Ullah, S.
creators_name: Ahmad, F.
creators_name: Shariff, A.M.
creators_name: Raza, M.R.
creators_name: Masset, P.J.
title: The role of multi-wall carbon nanotubes in char strength of epoxy based intumescent fire retardant coating
ispublished: pub
keywords: Coatings; Fire resistance; Fourier transform infrared spectroscopy; Pyrolysis; Scanning electron microscopy; Thermogravimetric analysis; Weathering; X ray diffraction; X ray photoelectron spectroscopy; Yarn, Expandable graphite; Intumescent fire retardant coatings; MWCNTs; Pyrolysis analysis; Weathering tests; XPS analysis, Multiwalled carbon nanotubes (MWCN)
note: cited By 39
abstract: Fire resistance of coatings mostly depends on the formation of char. In this work Multi-wall carbon nanotubes (MWCNTs) were used to improve fire retardant and char properties of the intumescent coating. Different coating formulations were prepared and their heat shielding performance was tested at 950 °C according to ASTM E-119. Char expansion was studied using fire furnace test. Field emission scanning electron microscope was used for char morphology. By means of X-ray Diffraction and Fourier transform infrared spectroscopy the presence of carbon, borophosphate; boron oxide and sassolite in the char was identified. Thermogravimetric analysis results showed that 0.5 wtMWCNTs enhanced the residual weight of char up to 29.35 wt. X-ray photoelectron spectroscopy (XPS) confirmed that 0.5 wt MWCNTs enhanced the carbon content up to 51.90 wt, lowering oxygen content to approximately 25 wt in the char that improved the fire resistance performance of the coating. Pyrolysis analysis confirmed that 0.5 wt MWCNTs formulation released less gaseous products and reduced the decomposition of gaseous products. An accelerated weathering test ASTM D 6695-03 also revealed that 0.5 wt of MWCNTs sustained its reliability up to 90 days in accelerated weathering chamber. © 2017 Elsevier B.V.
date: 2017
publisher: Elsevier B.V.
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85013113185&doi=10.1016%2fj.jaap.2017.02.011&partnerID=40&md5=bf262f6b14680260de0a7503c1cde657
id_number: 10.1016/j.jaap.2017.02.011
full_text_status: none
publication: Journal of Analytical and Applied Pyrolysis
volume: 124
pagerange: 149-160
refereed: TRUE
issn: 01652370
citation:   Ullah, S. and Ahmad, F. and Shariff, A.M. and Raza, M.R. and Masset, P.J.  (2017) The role of multi-wall carbon nanotubes in char strength of epoxy based intumescent fire retardant coating.  Journal of Analytical and Applied Pyrolysis, 124.  pp. 149-160.  ISSN 01652370