eprintid: 8605
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/86/05
datestamp: 2023-11-09 16:20:31
lastmod: 2023-11-09 16:20:31
status_changed: 2023-11-09 16:13:04
type: article
metadata_visibility: show
creators_name: Hassan, M.A.
creators_name: Komiyama, M.
title: Catalytic Partial Oxidation of Methane in Supercritical Water: A Domain in CH4/H2O-O2/CH4 Parameter Space Showing Significant Methane Coupling
ispublished: pub
keywords: Batch reactors; Catalysts; Catalytic oxidation; Hydrocarbons; Metals; Methanol; Molecular oxygen, Catalytic partial oxidation of methane; Metal oxide catalysts; Mixture of hydrocarbons; Oxidative coupling of methane; Partial oxidation of methane; Reaction temperature; Supercritical water; Transition-metal oxides, Methane
note: cited By 5
abstract: Partial oxidation of methane under supercritical water environment at 658 K and 26 MPa using a batch reactor was examined in the presence of metal oxide catalysts and H2O2 as a molecular oxygen source. Within a parameter space of feed concentrations (CH4/H2O and O2/CH4 ratios), there existed a domain that gave high C2+ hydrocarbon yield reaching ca. 4. Obtained products were a mixture of hydrocarbons up to C4 with ethane as a major component, accompanied by CO, CO2, H2, and methanol. The domain that gave high hydrocarbon yield did not coincide with that which gave high methanol yield. Catalyst survey indicated that transition-metal oxides are effective for the production of C2+ hydrocarbons under the present conditions. In view of the oxidative coupling of methane in all reaction modes explored previously, presently reported level of hydrocarbon yield is unprecedented at this low reaction temperature. (Graph Presented). © 2017 American Chemical Society.
date: 2017
publisher: American Chemical Society
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85021087332&doi=10.1021%2facs.iecr.7b00993&partnerID=40&md5=9fccb50f2ed77f7d5c3da0cf3547af72
id_number: 10.1021/acs.iecr.7b00993
full_text_status: none
publication: Industrial and Engineering Chemistry Research
volume: 56
number: 23
pagerange: 6618-6624
refereed: TRUE
issn: 08885885
citation:   Hassan, M.A. and Komiyama, M.  (2017) Catalytic Partial Oxidation of Methane in Supercritical Water: A Domain in CH4/H2O-O2/CH4 Parameter Space Showing Significant Methane Coupling.  Industrial and Engineering Chemistry Research, 56 (23).  pp. 6618-6624.  ISSN 08885885