eprintid: 8603 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/00/86/03 datestamp: 2023-11-09 16:20:31 lastmod: 2023-11-09 16:20:31 status_changed: 2023-11-09 16:13:04 type: article metadata_visibility: show creators_name: Ahmad, P. creators_name: Khandaker, M.U. creators_name: Muhammad, N. creators_name: Rehman, F. creators_name: Khan, G. creators_name: Rehman, M.A. creators_name: Ahmed, S.M. creators_name: Gulzar, M. creators_name: Numan, A. creators_name: Khan, A.S. title: Synthesis of multilayered hexagonal boron nitride microcrystals as a potential hydrogen storage element ispublished: pub keywords: Boron nitride; Crystalline materials; Crystals; Nitrides; Synthesis (chemical), BNMCs; Crystalline nature; Hexagonal boron nitride; Nitride powders; Potential hydrogens; Silicon substrates; Storage elements; Top down approaches, Hydrogen storage note: cited By 8 abstract: Top-down approach has been used to synthesize pure, highly crystalline, multilayered micron size crystals of hexagonal boron nitride (BNMCs) at the top of Silicon substrate at 800 °C by using bulk boron nitride powder as a precursor. The synthesized crystals have different interlayers spacing from left to right (0.33 nm, 0.37 nm and 0.35 nm) and at the center (~0.24 nm). The former spacing corresponds to d(002) spacing whereas the later corresponds to d(010) spacing in h-BN. The sharpness of the peaks in XRD, Raman and FTIR spectrums correspond to highly crystalline nature of BNMCs whereas the locations of the peaks verify the h-BN nature of BNMCs. The B-N bonded BNMCs with larger surface area can be an excellent choice as a hydrogen storage element. © 2017 Elsevier Ltd and Techna Group S.r.l. date: 2017 publisher: Elsevier Ltd official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85015698343&doi=10.1016%2fj.ceramint.2017.03.043&partnerID=40&md5=aca5f5e07d0d6184d0d810b28910d23a id_number: 10.1016/j.ceramint.2017.03.043 full_text_status: none publication: Ceramics International volume: 43 number: 9 pagerange: 7358-7361 refereed: TRUE issn: 02728842 citation: Ahmad, P. and Khandaker, M.U. and Muhammad, N. and Rehman, F. and Khan, G. and Rehman, M.A. and Ahmed, S.M. and Gulzar, M. and Numan, A. and Khan, A.S. (2017) Synthesis of multilayered hexagonal boron nitride microcrystals as a potential hydrogen storage element. Ceramics International, 43 (9). pp. 7358-7361. ISSN 02728842