TY - JOUR EP - 7361 PB - Elsevier Ltd SN - 02728842 N1 - cited By 8 SP - 7358 TI - Synthesis of multilayered hexagonal boron nitride microcrystals as a potential hydrogen storage element AV - none JF - Ceramics International A1 - Ahmad, P. A1 - Khandaker, M.U. A1 - Muhammad, N. A1 - Rehman, F. A1 - Khan, G. A1 - Rehman, M.A. A1 - Ahmed, S.M. A1 - Gulzar, M. A1 - Numan, A. A1 - Khan, A.S. UR - https://www.scopus.com/inward/record.uri?eid=2-s2.0-85015698343&doi=10.1016%2fj.ceramint.2017.03.043&partnerID=40&md5=aca5f5e07d0d6184d0d810b28910d23a VL - 43 Y1 - 2017/// IS - 9 N2 - Top-down approach has been used to synthesize pure, highly crystalline, multilayered micron size crystals of hexagonal boron nitride (BNMCs) at the top of Silicon substrate at 800 °C by using bulk boron nitride powder as a precursor. The synthesized crystals have different interlayers spacing from left to right (0.33 nm, 0.37 nm and 0.35 nm) and at the center (~0.24 nm). The former spacing corresponds to d(002) spacing whereas the later corresponds to d(010) spacing in h-BN. The sharpness of the peaks in XRD, Raman and FTIR spectrums correspond to highly crystalline nature of BNMCs whereas the locations of the peaks verify the h-BN nature of BNMCs. The B-N bonded BNMCs with larger surface area can be an excellent choice as a hydrogen storage element. © 2017 Elsevier Ltd and Techna Group S.r.l. ID - scholars8603 KW - Boron nitride; Crystalline materials; Crystals; Nitrides; Synthesis (chemical) KW - BNMCs; Crystalline nature; Hexagonal boron nitride; Nitride powders; Potential hydrogens; Silicon substrates; Storage elements; Top down approaches KW - Hydrogen storage ER -