eprintid: 8197
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/81/97
datestamp: 2023-11-09 16:20:04
lastmod: 2023-11-09 16:20:04
status_changed: 2023-11-09 16:12:02
type: article
metadata_visibility: show
creators_name: Yiin, C.L.
creators_name: Quitain, A.T.
creators_name: Yusup, S.
creators_name: Uemura, Y.
creators_name: Sasaki, M.
creators_name: Kida, T.
title: Choline chloride (ChCl) and monosodium glutamate (MSG)-based green solvents from optimized cactus malic acid for biomass delignification
ispublished: pub
keywords: choline; glutamate sodium; hydrogen peroxide; malic acid; malic acid derivative; solvent, biomass; Cactaceae; hydrolysis, Biomass; Cactaceae; Choline; Hydrogen Peroxide; Hydrolysis; Malates; Sodium Glutamate; Solvents
note: cited By 25
abstract: This work aimed to develop an efficient microwave-hydrothermal (MH) extraction of malic acid from abundant natural cactus as hydrogen bond donor (HBD) whereby the concentration was optimized using response surface methodology. The ideal process conditions were found to be at a solvent-to-feed ratio of 0.008, 120 °C and 20 min with 1.0 g of oxidant, H2O2. Next generation environment-friendly solvents, low transition temperature mixtures (LTTMs) were synthesized from cactus malic acid with choline chloride (ChCl) and monosodium glutamate (MSG) as hydrogen bond acceptors (HBAs). The hydrogen-bonding interactions between the starting materials were determined. The efficiency of the LTTMs in removing lignin from oil palm biomass residues, empty fruit bunch (EFB) was also evaluated. The removal of amorphous hemicellulose and lignin after the pretreatment process resulted in an enhanced digestibility and thermal degradability of biomass. © 2017 Elsevier Ltd
date: 2017
publisher: Elsevier Ltd
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85027836398&doi=10.1016%2fj.biortech.2017.08.043&partnerID=40&md5=314ede2a9a98d71ecbfb57fc7c166422
id_number: 10.1016/j.biortech.2017.08.043
full_text_status: none
publication: Bioresource Technology
volume: 244
pagerange: 941-948
refereed: TRUE
issn: 09608524
citation:   Yiin, C.L. and Quitain, A.T. and Yusup, S. and Uemura, Y. and Sasaki, M. and Kida, T.  (2017) Choline chloride (ChCl) and monosodium glutamate (MSG)-based green solvents from optimized cactus malic acid for biomass delignification.  Bioresource Technology, 244.  pp. 941-948.  ISSN 09608524