TY - JOUR Y1 - 2017/// VL - 244 JF - Bioresource Technology A1 - Yiin, C.L. A1 - Quitain, A.T. A1 - Yusup, S. A1 - Uemura, Y. A1 - Sasaki, M. A1 - Kida, T. UR - https://www.scopus.com/inward/record.uri?eid=2-s2.0-85027836398&doi=10.1016%2fj.biortech.2017.08.043&partnerID=40&md5=314ede2a9a98d71ecbfb57fc7c166422 ID - scholars8197 KW - choline; glutamate sodium; hydrogen peroxide; malic acid; malic acid derivative; solvent KW - biomass; Cactaceae; hydrolysis KW - Biomass; Cactaceae; Choline; Hydrogen Peroxide; Hydrolysis; Malates; Sodium Glutamate; Solvents N2 - This work aimed to develop an efficient microwave-hydrothermal (MH) extraction of malic acid from abundant natural cactus as hydrogen bond donor (HBD) whereby the concentration was optimized using response surface methodology. The ideal process conditions were found to be at a solvent-to-feed ratio of 0.008, 120 °C and 20 min with 1.0 g of oxidant, H2O2. Next generation environment-friendly solvents, low transition temperature mixtures (LTTMs) were synthesized from cactus malic acid with choline chloride (ChCl) and monosodium glutamate (MSG) as hydrogen bond acceptors (HBAs). The hydrogen-bonding interactions between the starting materials were determined. The efficiency of the LTTMs in removing lignin from oil palm biomass residues, empty fruit bunch (EFB) was also evaluated. The removal of amorphous hemicellulose and lignin after the pretreatment process resulted in an enhanced digestibility and thermal degradability of biomass. © 2017 Elsevier Ltd PB - Elsevier Ltd SN - 09608524 EP - 948 AV - none TI - Choline chloride (ChCl) and monosodium glutamate (MSG)-based green solvents from optimized cactus malic acid for biomass delignification SP - 941 N1 - cited By 25 ER -