TY - JOUR JF - Ceramics International IS - 1 SN - 02728842 N1 - cited By 38 TI - Surface modification of carbon nanofibers by HNO3 treatment N2 - A convenient and one-step surface modification method was developed to introduce different functional groups on the surface of herringbone type carbon nanofibers (CNFs) by treating with nitric acid solution. The modified CNFs were characterized by various techniques such as X-ray diffraction (XRD), nitrogen adsorptionâ??desorption isotherms (BET), thermo gravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy and Fourier transform infrared (FT-IR). The XRD studies revealed intensification of graphitization in CNFs as a function of nitric acid treatment. Similarly, the surface modification of CNFs led to enhance the BET surface area from of 112 to 152 m2/g. The XPS investigations indicated the existence of alcoholic (Câ??OH) and carbonyl (CdbndO) functional groups on the surface of modified CNFs. Moreover, FT-IR studies confirmed the generation of carboxylate, hydroxyl and alcoholic functional groups on the surface of acid-treated CNFs. © 2015 Elsevier Ltd and Techna Group S.r.l. ID - scholars8016 UR - https://www.scopus.com/inward/record.uri?eid=2-s2.0-84947483896&doi=10.1016%2fj.ceramint.2015.08.054&partnerID=40&md5=a6b4f74545304c6a75d583227c5b804f EP - 970 KW - Carbon nanofibers; Carboxylation; Gas adsorption; Gravimetric analysis; Nanofibers; Nitric acid; Oxidation; Surface treatment; Thermogravimetric analysis; X ray diffraction KW - Acid treated; Acid treatments; BET surface area; Carbon material; Fourier transform infrared; Nitric acid solutions; Nitric acid treatment; Nitrogen adsorption desorption isotherms KW - X ray photoelectron spectroscopy A1 - Ud Din, I. A1 - Shaharun, M.S. A1 - Subbarao, D. A1 - Naeem, A. SP - 966 PB - Elsevier Ltd AV - none Y1 - 2016/// VL - 42 ER -