eprintid: 7999 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/00/79/99 datestamp: 2023-11-09 16:19:51 lastmod: 2023-11-09 16:19:51 status_changed: 2023-11-09 16:10:55 type: article metadata_visibility: show creators_name: Farooq, M. creators_name: Ramli, A. creators_name: Naeem, A. creators_name: Saleem Khan, M. title: Effect of different metal oxides on the catalytic activity of γ-Al2O3-MgO supported bifunctional heterogeneous catalyst in biodiesel production from WCO ispublished: pub keywords: Aluminum; Biodiesel; Catalyst supports; Catalysts; Magnesia; Manganese; Oils and fats; Reusability; Synthetic fuels, Biodiesel production; Characterization techniques; Heterogeneous catalyst; Operation conditions; Optimal reaction condition; Physicochemical property; Reaction temperature; Transesterification reaction, Catalyst activity note: cited By 24 abstract: The catalytic activity of different γ-Al2O3-MgO supported bifunctional solid catalysts was successfully evaluated by carrying out simultaneous esterification-transesterification reactions in waste cooking oil. The physicochemical properties of the synthesized catalysts were studied using different characterization techniques to identify a catalyst of proper configuration for proper operation conditions to develop a sustainable and economical biodiesel production process. The results indicated that the Mo-Mn/γ-Al2O3-15 wt MgO catalyst showed excellent performance in biodiesel production from selected waste cooking oil as compared with Mo-Zn/γ-Al2O3-15 wt MgO or Mo-Sn/γ-Al2O3-15 wt MgO catalysts and provided a biodiesel yield of 91.4 under optimal reaction conditions, i.e. methanol/oil molar ratio of 27:1, 5 wt catalyst and a reaction temperature of 100 °C for 4 h. The good catalytic activity could be attributed to the existence of the optimal number of catalytically active sites on the surface of the catalyst. Moreover, the catalyst showed substantial reusability in biodiesel production from waste cooking oil. © 2016 The Royal Society of Chemistry. date: 2016 publisher: Royal Society of Chemistry official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84954194287&doi=10.1039%2fc5ra18146a&partnerID=40&md5=ad690213f756dbf49b32b104c92c921d id_number: 10.1039/c5ra18146a full_text_status: none publication: RSC Advances volume: 6 number: 2 pagerange: 505-512 refereed: TRUE issn: 20462069 citation: Farooq, M. and Ramli, A. and Naeem, A. and Saleem Khan, M. (2016) Effect of different metal oxides on the catalytic activity of γ-Al2O3-MgO supported bifunctional heterogeneous catalyst in biodiesel production from WCO. RSC Advances, 6 (2). pp. 505-512. ISSN 20462069