eprintid: 7850
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/78/50
datestamp: 2023-11-09 16:19:41
lastmod: 2023-11-09 16:19:41
status_changed: 2023-11-09 16:10:34
type: article
metadata_visibility: show
creators_name: Lee, S.-P.
creators_name: Mellon, N.
creators_name: Lau, T.K.
creators_name: Shariff, A.M.
creators_name: Leveque, J.-M.
title: Synthesis and characterization of covalent organic polymer
ispublished: pub
keywords: Chemical stability; Chlorine compounds; Fourier transform infrared spectroscopy; Gas adsorption; Gravimetric analysis; Mesoporous materials; Nuclear magnetic resonance; Pore size; Thermogravimetric analysis, Covalent organic polymer (COP); Cyanuric chloride; Fourier transform infra reds; FTIR; Hydrothermal stabilities; Synthesis and characterizations; Thermal degradation temperatures; Thermal gravimetric analyses (TGA), Organic polymers
note: cited By 1; Conference of 2nd International Conference on Science and Engineering of Materials, ICoSEM 2015 ; Conference Date: 16 November 2015 Through 18 November 2015; Conference Code:178689
abstract: Development of covalent organic polymer (COP) is a potential new class of adsorbent for gas separation due to their good hydrothermal stability, chemical tuning flexibility and low cost. COP-1 was prepared via one-step polycondensation of cyanuric chloride and piperazine under catalyst free and N2 atmosphere condition. The properties of COP-1 were characterized using several analytical methods such as Fourier Transform Infra-Red (FTIR), solid Nuclear Magnetic Resonance (s-NMR), Thermal gravimetric analysis (TGA) and N2 adsorption and desorption measurement. The C-N bond of COP-1 which has non-rigid framework was successfully linked in this study. It is found that COP-1 has low thermal degradation temperature i.e. 483 K. As compared to literature, lower surface area (75.5 m2/g) and slightly large pore size (8 nm) are noticed. The difference of physical properties of COP-1 synthesized between in this study and literature revealed the challenge of reproducibility for COP-1. © 2016 Trans Tech Publications, Switzerland.
date: 2016
publisher: Trans Tech Publications Ltd
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84979554540&doi=10.4028%2fwww.scientific.net%2fKEM.701.270&partnerID=40&md5=c57dbe562e69f42e71436533c97f9240
id_number: 10.4028/www.scientific.net/KEM.701.270
full_text_status: none
publication: Key Engineering Materials
volume: 701
pagerange: 270-274
refereed: TRUE
isbn: 9783038356875
issn: 10139826
citation:   Lee, S.-P. and Mellon, N. and Lau, T.K. and Shariff, A.M. and Leveque, J.-M.  (2016) Synthesis and characterization of covalent organic polymer.  Key Engineering Materials, 701.  pp. 270-274.  ISSN 10139826