TY  - JOUR
VL  - 701
JF  - Key Engineering Materials
N1  - cited By 1; Conference of 2nd International Conference on Science and Engineering of Materials, ICoSEM 2015 ; Conference Date: 16 November 2015 Through 18 November 2015; Conference Code:178689
UR  - https://www.scopus.com/inward/record.uri?eid=2-s2.0-84979554540&doi=10.4028%2fwww.scientific.net%2fKEM.701.270&partnerID=40&md5=c57dbe562e69f42e71436533c97f9240
A1  - Lee, S.-P.
A1  - Mellon, N.
A1  - Lau, T.K.
A1  - Shariff, A.M.
A1  - Leveque, J.-M.
Y1  - 2016///
PB  - Trans Tech Publications Ltd
SP  - 270
AV  - none
ID  - scholars7850
EP  - 274
SN  - 10139826
N2  - Development of covalent organic polymer (COP) is a potential new class of adsorbent for gas separation due to their good hydrothermal stability, chemical tuning flexibility and low cost. COP-1 was prepared via one-step polycondensation of cyanuric chloride and piperazine under catalyst free and N2 atmosphere condition. The properties of COP-1 were characterized using several analytical methods such as Fourier Transform Infra-Red (FTIR), solid Nuclear Magnetic Resonance (s-NMR), Thermal gravimetric analysis (TGA) and N2 adsorption and desorption measurement. The C-N bond of COP-1 which has non-rigid framework was successfully linked in this study. It is found that COP-1 has low thermal degradation temperature i.e. 483 K. As compared to literature, lower surface area (75.5 m2/g) and slightly large pore size (8 nm) are noticed. The difference of physical properties of COP-1 synthesized between in this study and literature revealed the challenge of reproducibility for COP-1. © 2016 Trans Tech Publications, Switzerland.
KW  - Chemical stability; Chlorine compounds; Fourier transform infrared spectroscopy; Gas adsorption; Gravimetric analysis; Mesoporous materials; Nuclear magnetic resonance; Pore size; Thermogravimetric analysis
KW  -  Covalent organic polymer (COP); Cyanuric chloride; Fourier transform infra reds; FTIR; Hydrothermal stabilities; Synthesis and characterizations; Thermal degradation temperatures; Thermal gravimetric analyses (TGA)
KW  -  Organic polymers
TI  - Synthesis and characterization of covalent organic polymer
ER  -