eprintid: 754
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/07/54
datestamp: 2023-11-09 15:48:54
lastmod: 2023-11-09 15:48:54
status_changed: 2023-11-09 15:23:06
type: article
metadata_visibility: show
creators_name: Abdullah, M.A.
creators_name: Chiang, L.
creators_name: Nadeem, M.
title: Comparative evaluation of adsorption kinetics and isotherms of a natural product removal by Amberlite polymeric adsorbents
ispublished: pub
keywords: Adsorption isotherms; Alizarin; Kinetics; Least squares approximations; Linear regression; Microporosity; Polymers; Solutions, Adsorption kinetics; Adsorption kinetics and isotherm; Comparative evaluations; Isotherm models; Non-linear regression; Non-linear regression method; Polymeric adsorbent; Pseudo second order kinetics, Adsorption
note: cited By 118
abstract: Adsorption mechanism of a natural compound, alizarin (1,2-dihydroxyanthraquinone), onto three types of microporous polymeric adsorbents (XAD-4, XAD-7, XAD-16) has been proposed using Langmuir, Freundlich and Redlich-Petersen isotherms. Adsorption capacity and optimum adsorption isotherms were predicted by linear least squares and non-linear regression method. Adsorption kinetics was proposed by pseudo-first and second second order models. The adsorption capacity of XAD-16 was the highest at 0.0424 mg/mg, with initial alizarin concentration of 200 mg/L. Pseudo-second-order kinetics was more appropriate in explaining the adsorption mechanism than pseudo-first-order. Over the studied concentration ranges, only XAD-4 adsorption can be reasonably described by the three isotherms. XAD-16 data is only best-fitted to Langmuir and Redlich-Petersen isotherms. Non-linear method proved a better way to predict the equilibrium isotherm parameters. The combination of parameters, such as specific surface area, pore diameter, polarity of the network of the resins, the solubility and polarity of the adsorbate, are the significant parameters for optimum adsorption process. Crown Copyright © 2008.
date: 2009
publisher: Elsevier
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-58349087399&doi=10.1016%2fj.cej.2008.06.018&partnerID=40&md5=13a3a0b77a597cdb4864603660be1ee8
id_number: 10.1016/j.cej.2008.06.018
full_text_status: none
publication: Chemical Engineering Journal
volume: 146
number: 3
pagerange: 370-376
refereed: TRUE
issn: 13858947
citation:   Abdullah, M.A. and Chiang, L. and Nadeem, M.  (2009) Comparative evaluation of adsorption kinetics and isotherms of a natural product removal by Amberlite polymeric adsorbents.  Chemical Engineering Journal, 146 (3).  pp. 370-376.  ISSN 13858947