eprintid: 7507 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/00/75/07 datestamp: 2023-11-09 16:19:19 lastmod: 2023-11-09 16:19:19 status_changed: 2023-11-09 16:09:36 type: conference_item metadata_visibility: show creators_name: Chew, T.L. creators_name: Ahmad, A.L. title: Gas Permeation Properties of Modified SAPO-34 Zeolite Membranes ispublished: pub keywords: Carbon; Carbon dioxide; Gases; Membrane technology; Membranes; Permeation; Process engineering; Zeolites, CH4; Gas permeation; Gas permeation properties; Membrane separation technology; SAPO-34; Separation performance; Silicoaluminophosphates; Zeolite membrane, Gas permeable membranes note: cited By 9; Conference of 4th International Conference on Process Engineering and Advanced Materials, ICPEAM 2016 ; Conference Date: 15 August 2016 Through 17 August 2016; Conference Code:131138 abstract: The global concern to reduce carbon dioxide (CO2) gas emission urges the need to explore for the effective membrane separation technology. Gas permeation properties of the membranes are good indicator in reflecting the gas mixture's separation performance of the membranes. Nowadays, silicoaluminophosphate-34 (SAPO-34) zeolite membrane is gaining increasing popularity among researchers in gas permeations studies due to their small pore structure. In current study, the synthesized SAPO-34 zeolite membrane was modified with Ba2+ cation to form Ba-SAPO-34 membrane. CO2 and CH4 gas permeation studies for the Ba-SAPO-34 zeolite membrane were carried out at temperature of 30 - 180 oC and pressure difference of 100 - 500 kPa. The effect of temperature and pressure difference on the gas permeation properties of the Ba-SAPO-34 zeolite membranes was investigated. When the pressure difference was increased from 100 to 500 kPa at 30 oC, the CO2 flux and CH4 flux increased from 19.5 to 78.7�10-3 mol/m2·s and from 0.35 to 1.75�10-3 mol/m2·s respectively. When the temperature was increased from 30 to 180 oC at pressure difference of 100 kPa, the CO2 flux decreased from 19.5 to 9.8�10-3 mol/m2·s but the CH4 flux remained nearly constant at 0.35�10-3 mol/m2·s. CO2/CH4 ideal selectivity as high as �56 was obtained for Ba-SAPO-34 membrane's gas permeation at 30 oC and 100 kPa pressure difference. © 2016 Published by Elsevier Ltd. date: 2016 publisher: Elsevier Ltd official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85013868865&doi=10.1016%2fj.proeng.2016.06.471&partnerID=40&md5=dfbecf18af16d31b6657eedd8d449b8d id_number: 10.1016/j.proeng.2016.06.471 full_text_status: none publication: Procedia Engineering volume: 148 pagerange: 1225-1231 refereed: TRUE issn: 18777058 citation: Chew, T.L. and Ahmad, A.L. (2016) Gas Permeation Properties of Modified SAPO-34 Zeolite Membranes. In: UNSPECIFIED.