eprintid: 7498
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/74/98
datestamp: 2023-11-09 16:19:18
lastmod: 2023-11-09 16:19:18
status_changed: 2023-11-09 16:09:34
type: conference_item
metadata_visibility: show
creators_name: Omoregbe, O.
creators_name: Danh, H.T.
creators_name: Abidin, S.Z.
creators_name: Setiabudi, H.D.
creators_name: Abdullah, B.
creators_name: Vu, K.B.
creators_name: Vo, D.-V.N.
title: Influence of Lanthanide Promoters on Ni/SBA-15 Catalysts for Syngas Production by Methane Dry Reforming
ispublished: pub
keywords: Carbon; Carbon dioxide; Catalytic reforming; Chemical reactors; Crystallite size; Doping (additives); Fischer-Tropsch synthesis; Methane; Nickel; Process engineering; Synthesis gas, CeO2 promoter; Methane dry reforming; Ni-based catalyst; SBA-15; Syn-gas, Catalysts
note: cited By 50; Conference of 4th International Conference on Process Engineering and Advanced Materials, ICPEAM 2016 ; Conference Date: 15 August 2016 Through 17 August 2016; Conference Code:131138
abstract: The catalytic performance of Ce- and La-promoted Ni/SBA-15 catalysts for syngas production from CO2 reforming of methane has been investigated in a fixed-bed reactor at stoichiometric feed composition. Both promoted and unpromoted catalysts possessed high BET surface area of 303-445 m2 g-1. Additionally, SBA-15 support had a relatively uniform rod-like shape with a diameter of about 0.55 μm and a reduction in the crystallite size of NiO phase from 27.0 to 19.1 nm was observed with promoter addition reasonably due to the strong interaction between promoter and NiO particles. CeO2 and La2O3 dopants were finely dispersed on catalyst surface. Temperature-programmed oxidation of spent catalysts showed that coke-resistance was improved significantly with promoter modification and 3La-10Ni/SBA-15 catalyst was the most resistant to carbonaceous deposition rationally due to the least NiO crystallite size hindering the nucleation and growth of graphitic carbon. Hence, La-promoted catalyst appeared to be the optimum catalyst in terms of reactant conversion, H2 yield and stability whilst a gradual decline in both reactant conversion and H2 yield was experienced with unpromoted and Ce-doped catalysts. Regardless of catalyst types, the ratio of H2 to CO was always less than unity preferred for Fischer-Tropsch synthesis. © 2016 The Authors.
date: 2016
publisher: Elsevier Ltd
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85013882615&doi=10.1016%2fj.proeng.2016.06.556&partnerID=40&md5=a83ae641970c06ce8fa6eb428577304e
id_number: 10.1016/j.proeng.2016.06.556
full_text_status: none
publication: Procedia Engineering
volume: 148
pagerange: 1388-1395
refereed: TRUE
issn: 18777058
citation:   Omoregbe, O. and Danh, H.T. and Abidin, S.Z. and Setiabudi, H.D. and Abdullah, B. and Vu, K.B. and Vo, D.-V.N.  (2016) Influence of Lanthanide Promoters on Ni/SBA-15 Catalysts for Syngas Production by Methane Dry Reforming.  In: UNSPECIFIED.