<> <http://www.w3.org/2000/01/rdf-schema#comment> "The repository administrator has not yet configured an RDF license."^^<http://www.w3.org/2001/XMLSchema#string> . <> <http://xmlns.com/foaf/0.1/primaryTopic> <https://khub.utp.edu.my/scholars/id/eprint/7397> . <https://khub.utp.edu.my/scholars/id/eprint/7397> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/AcademicArticle> . <https://khub.utp.edu.my/scholars/id/eprint/7397> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/Article> . <https://khub.utp.edu.my/scholars/id/eprint/7397> <http://purl.org/dc/terms/title> "Total Acid Number Reduction of 2, 6-Naphthalenedicarboxylic Acid Using Subcritical Methanol for Reducing Acidity of Heavy Oil: A Kinetic Study"^^<http://www.w3.org/2001/XMLSchema#string> . <https://khub.utp.edu.my/scholars/id/eprint/7397> <http://purl.org/ontology/bibo/abstract> "Naphthenic acid (NA) found in hydrocarbon deposits is responsible for acidity of petroleum oils. In this study, a model compound of NAs, 2, 6-Naphthalenedicarboxylic acid (NDCA), is used for total acid number (TAN) reduction kinetic analysis. This goal of this paper is to investigate the capability of subcritical methanol (SubC-MeOH) for reducing acidity of NDCA without the addition of any catalyst or additives. The reaction kinetics is also discovered for large scale reactor design. The experiments were carried out in a 25 ml autoclave reactor (China) at temperatures of 180-220oC, a methanol partial pressure (MPP) of 0.1 MPa, reaction times of 0-60 min and a NDCA initial gas phase concentration of 0.03 g/mL. The TAN content of the samples were analyzed using American Society for Testing Materials (ASTM) D 974 techniques. The reaction products were identified and quantified with the help of GC/MS and GC-FID respectively. Experimental results reveal that TAN reduction of NDCA was increasing with increasing reaction temperature and time. Approximately, 52.12 TAN was reduced at a temperature of 220oC, a MPP of 0.1 MPa, and a reaction time of 60 min. Experimental data revealed that TAN removal reaction kinetics followed second order kinetics with an activation energy of 8.24 kcal/mol and a pre-exponential factor of 2.087 fraction-1s-1. Therefore, SubC-MeOH is capable to reduce TAN of NDCA without the addition of any catalyst or additives. © 2016 Published by Elsevier Ltd."^^<http://www.w3.org/2001/XMLSchema#string> . <https://khub.utp.edu.my/scholars/id/eprint/7397> <http://purl.org/dc/terms/date> "2016" . <https://khub.utp.edu.my/scholars/id/eprint/7397> <http://www.w3.org/2002/07/owl#sameAs> <https://doi.org/10.1016/j.proeng.2016.06.454> . <https://khub.utp.edu.my/scholars/id/eprint/7397> <http://purl.org/ontology/bibo/volume> "148" . <https://khub.utp.edu.my/scholars/id/org/ext-55dc687e68eb8d225f9aa9669e2e8677> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Organization> . <https://khub.utp.edu.my/scholars/id/org/ext-55dc687e68eb8d225f9aa9669e2e8677> <http://xmlns.com/foaf/0.1/name> "Elsevier Ltd"^^<http://www.w3.org/2001/XMLSchema#string> . <https://khub.utp.edu.my/scholars/id/eprint/7397> <http://purl.org/dc/terms/publisher> <https://khub.utp.edu.my/scholars/id/org/ext-55dc687e68eb8d225f9aa9669e2e8677> . <https://khub.utp.edu.my/scholars/id/publication/ext-18777058> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/Collection> . <https://khub.utp.edu.my/scholars/id/publication/ext-18777058> <http://xmlns.com/foaf/0.1/name> "Procedia Engineering"^^<http://www.w3.org/2001/XMLSchema#string> . <https://khub.utp.edu.my/scholars/id/eprint/7397> <http://purl.org/dc/terms/isPartOf> <https://khub.utp.edu.my/scholars/id/publication/ext-18777058> . <https://khub.utp.edu.my/scholars/id/publication/ext-18777058> <http://www.w3.org/2002/07/owl#sameAs> <urn:issn:18777058> . <https://khub.utp.edu.my/scholars/id/publication/ext-18777058> <http://purl.org/ontology/bibo/issn> "18777058" . <https://khub.utp.edu.my/scholars/id/eprint/7397> <http://purl.org/ontology/bibo/status> <http://purl.org/ontology/bibo/status/peerReviewed> . <https://khub.utp.edu.my/scholars/id/eprint/7397> <http://purl.org/ontology/bibo/status> <http://purl.org/ontology/bibo/status/published> . <https://khub.utp.edu.my/scholars/id/eprint/7397> <http://purl.org/dc/terms/creator> <https://khub.utp.edu.my/scholars/id/person/ext-8b10e60a819dde50914e2d2760711f58> . <https://khub.utp.edu.my/scholars/id/eprint/7397> <http://purl.org/ontology/bibo/authorList> <https://khub.utp.edu.my/scholars/id/eprint/7397#authors> . <https://khub.utp.edu.my/scholars/id/eprint/7397#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_1> <https://khub.utp.edu.my/scholars/id/person/ext-8b10e60a819dde50914e2d2760711f58> . <https://khub.utp.edu.my/scholars/id/eprint/7397> <http://purl.org/dc/terms/creator> <https://khub.utp.edu.my/scholars/id/person/ext-7b1fa846cee35dab8301350032fe83c6> . <https://khub.utp.edu.my/scholars/id/eprint/7397> <http://purl.org/ontology/bibo/authorList> <https://khub.utp.edu.my/scholars/id/eprint/7397#authors> . <https://khub.utp.edu.my/scholars/id/eprint/7397#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_2> <https://khub.utp.edu.my/scholars/id/person/ext-7b1fa846cee35dab8301350032fe83c6> . <https://khub.utp.edu.my/scholars/id/eprint/7397> <http://purl.org/dc/terms/creator> <https://khub.utp.edu.my/scholars/id/person/ext-870dd1aa64a2883aca18fea17fda3cb7> . <https://khub.utp.edu.my/scholars/id/eprint/7397> <http://purl.org/ontology/bibo/authorList> <https://khub.utp.edu.my/scholars/id/eprint/7397#authors> . <https://khub.utp.edu.my/scholars/id/eprint/7397#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_3> <https://khub.utp.edu.my/scholars/id/person/ext-870dd1aa64a2883aca18fea17fda3cb7> . <https://khub.utp.edu.my/scholars/id/person/ext-7b1fa846cee35dab8301350032fe83c6> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://khub.utp.edu.my/scholars/id/person/ext-7b1fa846cee35dab8301350032fe83c6> <http://xmlns.com/foaf/0.1/givenName> "A.B."^^<http://www.w3.org/2001/XMLSchema#string> . <https://khub.utp.edu.my/scholars/id/person/ext-7b1fa846cee35dab8301350032fe83c6> <http://xmlns.com/foaf/0.1/familyName> "Abdullah"^^<http://www.w3.org/2001/XMLSchema#string> . <https://khub.utp.edu.my/scholars/id/person/ext-7b1fa846cee35dab8301350032fe83c6> <http://xmlns.com/foaf/0.1/name> "A.B. 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