eprintid: 737
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/07/37
datestamp: 2023-11-09 15:48:53
lastmod: 2023-11-09 15:48:53
status_changed: 2023-11-09 15:23:04
type: article
metadata_visibility: show
creators_name: Perumalsamy, M.
creators_name: Murugesan, T.
title: Phase compositions, molar mass, and temperature effect on densities, viscosities, and liquid-liquid equilibrium of polyethylene glycol and salt-based aqueous two-phase systems
ispublished: pub
keywords: Aqueous solutions; Aqueous two-phase systems; Density datum; Equilibrium compositions; Linear variations; Liquid-liquid equilibrium; Mass fractions; Mean deviations; Polyethylene glycol 4000; Sodium citrates; Temperature effects; Tie lines; Two-phase systems; Viscosity datum, Ethylene glycol; Liquids; Nonlinear equations; Phase equilibria; Polyethylene glycols; Thermal effects; Thermoplastics; Viscometers; Viscosity, Polyethylene oxides
note: cited By 36
abstract: Densities and viscosities of aqueous solutions of polyethylene glycol 4000 mass fraction from (5 to 50) % have been measured at different temperatures, (298.15, 303.15, 308.15, 313.15, and 318.15) K. The density data show a linear variation with mass fraction of the polymer for all temperatures. The viscosity data of PEG 4000 solutions were correlated as a function of mass fraction, using a nonlinear equation, for the five different temperatures covered in the present work. Densities, viscosities, and liquid - liquid equilibria of polyethylene glycol - sodium citrate two-phase systems have been measured and are correlated with compositions at (298.15, 308.15, and 318.15) K. The effect of tie line lengths on density and viscosity of the aqueous two-phase systems has also been represented. The tie lines were correlated using the Othmer - Tobias and Bancraft equations as well as the virial equation. The coefficients were estimated and reported. The mean deviations between the experimental and calculated equilibrium compositions in the top and bottom phases were < 1 %. © 2009 American Chemical Society.
date: 2009
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-65449168393&doi=10.1021%2fje801004n&partnerID=40&md5=a093a36dec893c32da2037cdf9188e2c
id_number: 10.1021/je801004n
full_text_status: none
publication: Journal of Chemical and Engineering Data
volume: 54
number: 4
pagerange: 1359-1366
refereed: TRUE
issn: 00219568
citation:   Perumalsamy, M. and Murugesan, T.  (2009) Phase compositions, molar mass, and temperature effect on densities, viscosities, and liquid-liquid equilibrium of polyethylene glycol and salt-based aqueous two-phase systems.  Journal of Chemical and Engineering Data, 54 (4).  pp. 1359-1366.  ISSN 00219568