eprintid: 7243
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/72/43
datestamp: 2023-11-09 16:19:02
lastmod: 2023-11-09 16:19:02
status_changed: 2023-11-09 16:08:51
type: article
metadata_visibility: show
creators_name: Nasir Shah, S.
creators_name: Kallidanthiyil Chellappan, L.
creators_name: Gonfa, G.
creators_name: Mutalib, M.I.A.
creators_name: Pilus, R.B.M.
creators_name: Bustam, M.A.
title: Extraction of naphthenic acid from highly acidic oil using phenolate based ionic liquids
ispublished: pub
keywords: Crude oil; Extraction; Liquids; Negative ions; Organic acids; Reusability, Alkyl chain lengths; Alkyl methyl imidazole; Deacidification; Extraction efficiencies; Heavy crude oil; Imidazolium cation; Imidazolium ionic liquids; Naphthenic acid, Ionic liquids
note: cited By 66
abstract: In this study, N-alkyl imidazolium ionic liquids with highly alkaline phenolate anions were used for the removal of naphthenic acid from model acid oil. The effect of alkyl spacer length on the deacidification process was evaluated by attaching butyl, hexyl, octyl, decyl and dodecyl groups on imidazolium cation. It was found that increase in the alkyl chain length increases the percent naphthenic acid removal. Extremely low amount of ionic liquids were necessary for the complete deacidification of model oil with high TAN. The reusability of the phenolate ionic liquids was also investigated. COSMO-RS calculations were performed on phenolate ionic liquids to study their extraction efficiency, selectivity and solvent capacity. © 2015 Elsevier B.V.
date: 2016
publisher: Elsevier
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84942765400&doi=10.1016%2fj.cej.2015.09.017&partnerID=40&md5=e70f459689afad5177b5da222e25a61c
id_number: 10.1016/j.cej.2015.09.017
full_text_status: none
publication: Chemical Engineering Journal
volume: 284
pagerange: 487-493
refereed: TRUE
issn: 13858947
citation:   Nasir Shah, S. and Kallidanthiyil Chellappan, L. and Gonfa, G. and Mutalib, M.I.A. and Pilus, R.B.M. and Bustam, M.A.  (2016) Extraction of naphthenic acid from highly acidic oil using phenolate based ionic liquids.  Chemical Engineering Journal, 284.  pp. 487-493.  ISSN 13858947