@article{scholars7135, pages = {5146--5154}, doi = {10.1080/19443994.2014.1001441}, number = {11}, title = {Degradation of chlorpyrifos, cypermethrin and chlorothalonil pesticides in aqueous solution by FeGAC/H2O2 process}, volume = {57}, year = {2016}, journal = {Desalination and Water Treatment}, publisher = {Taylor and Francis Inc.}, note = {cited By 12}, author = {Affam, A. C. and Chaudhuri, M. and Kutty, S. R. M. and Muda, K.}, issn = {19443994}, url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-84955204191&doi=10.1080\%2f19443994.2014.1001441&partnerID=40&md5=8fe5dca46c868d51d49944cd766b6cf3}, abstract = {This study examined the degradation of pesticide aqueous solution containing chlorpyrifos, cypermethrin and chlorothalonil by the FeGAC/H2O2 process. Under the operating conditions (FeGAC 5{\^A} g/L, H2O2 concentration 100{\^A} mg/L and pH 3), chemical oxygen demand (COD) and total organic carbon removal were 96.2 and 79.2, respectively, and biodegradability (BOD5/COD ratio) increased from 0 to 0.40 after 60 min reaction. Complete degradation of chlorpyrifos, cypermethrin and chlorothalonil pesticides active ingredients occurred in 1{\^A} min. Kinetic models such as pseudo-first-order, pseudo-second-order and intraparticle diffusion were evaluated. The Fourier transform infrared spectra (treated and untreated pesticide aqueous solutions) also indicated modification and/or degradation of the pesticide organic bonds. The study showed that FeGAC/H2O2 process can be used for the pretreatment of pesticide aqueous solution containing chlorpyrifos, cypermethrin and chlorothalonil before further treatment by biological process. {\^A}{\copyright} 2015 Balaban Desalination Publications. All rights reserved.} }