eprintid: 7055
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/70/55
datestamp: 2023-11-09 16:18:51
lastmod: 2023-11-09 16:18:51
status_changed: 2023-11-09 16:08:22
type: article
metadata_visibility: show
creators_name: Alhassan, F.H.
creators_name: Rashid, U.
creators_name: Taufiq-Yap, Y.H.
title: Optimization of simultaneous production of waste cooking oil based-biodiesel using iron-manganese doped zirconia-supported molybdenum oxide nanoparticles catalyst
ispublished: pub
keywords: Biodiesel; Catalyst activity; Catalysts; Cooking; Diesel fuels; Esters; Manganese; Manganese oxide; Molybdenum; Molybdenum oxide; Oils and fats; Synthetic fuels; Thermal processing (foods); Thermogravimetric analysis; Transesterification; Zirconia, Biodiesel production; Central composite designs; Impregnation methods; Molybdenum oxide catalysts; Optimization studies; Physicochemical property; Response surface methodology; Trans-esterification methods, Catalyst supports
note: cited By 11
abstract: Biodiesel derived from simultaneous esterification and transesterification of waste cooking oil has been attracting consideration as a replacement green fuel for diesel fuels, as it is economically feasible and circumvents the issue of energy versus food, which is estimated to take place with current biodiesel production techniques. In this optimization study, iron-manganese doped zirconia-supported molybdenum oxide catalyst has been prepared and used in the synthesis of waste cooking oil based biodiesel by a simultaneous esterification and transesterification method. The catalyst is prepared via an impregnation method and consequently characterized by XRD, TEM, TGA (thermogravimetric analysis), TPD-NH3, and Brunauer-Emmer-Teller (BET) techniques. The simultaneous process for biodiesel production has been assessed and improved statistically via response surface methodology in combination with the central composite design. It has been established that the process for synthesis of waste cooking oil based biodiesel achieved about 96.8 biodiesel yield at a best condition of 200 °C, waste cooking oil/ methanol molar ratio of 1:30 and 5.0 wt.  as loading of the catalyst. The highest ester yield of 96.8 has been obtained due to the improved physicochemical properties of zirconia-supported molybdenum oxide catalyst which accesses diffusion of the reactants to the active sites. © 2016 Author(s).
date: 2016
publisher: American Institute of Physics Inc.
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84974559579&doi=10.1063%2f1.4953090&partnerID=40&md5=d430a8e23511493070450cf627a4f18e
id_number: 10.1063/1.4953090
full_text_status: none
publication: Journal of Renewable and Sustainable Energy
volume: 8
number: 3
refereed: TRUE
issn: 19417012
citation:   Alhassan, F.H. and Rashid, U. and Taufiq-Yap, Y.H.  (2016) Optimization of simultaneous production of waste cooking oil based-biodiesel using iron-manganese doped zirconia-supported molybdenum oxide nanoparticles catalyst.  Journal of Renewable and Sustainable Energy, 8 (3).   ISSN 19417012