eprintid: 6907
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/69/07
datestamp: 2023-11-09 16:18:42
lastmod: 2023-11-09 16:18:42
status_changed: 2023-11-09 16:07:58
type: article
metadata_visibility: show
creators_name: Abbas, T.
creators_name: Gonfa, G.
creators_name: Lethesh, K.C.
creators_name: Mutalib, M.I.A.
creators_name: Abai, M.B.
creators_name: Cheun, K.Y.
creators_name: Khan, E.
title: Mercury capture from natural gas by carbon supported ionic liquids: Synthesis, evaluation and molecular mechanism
ispublished: pub
keywords: Activated carbon; Adsorption; Field emission microscopes; Flow of gases; Fourier transform infrared spectroscopy; Liquids; Mercury (metal); Molecular structure; Nuclear magnetic resonance spectroscopy; Scanning electron microscopy; Silica; X ray photoelectron spectroscopy, 1-Butyl-3-methylimidazolium chloride; Brunauer-emmett-teller surface areas; Elemental mercury; Energy dispersive x-ray; Field emission scanning electron microscopy; Molecular level interactions; Molecular simulations; Supported ionic liquids, Ionic liquids
note: cited By 34
abstract: Superiority of silica supported ionic liquids over other adsorbents in capturing elemental mercury (Hg0) from flue gases has been recently reported. In this study, activated carbon, which is more economical than silica, was experimented as a solid support for ionic liquids (ILs) for gaseous Hg0 removal. Four ILs were successfully coated on activated carbon. The carbon supported ionic liquids (CSILs) were characterized by Fourier transform infrared spectroscopy, Brunauer-Emmett-Teller surface area analysis, field emission scanning electron microscopy, energy-dispersive X-ray, X ray-photoelectron spectroscopy and nuclear magnetic resonance. A continuous fixed bed flow reactor was used to examine the performance of CSILs in treating 20-35 ppm Hg0 vapor at a gas flow rate of 60 mL/min. 1-Butyl-3-methylimidazolium chloride BmimCl coated activated carbon was the most reactive among CSILs studied and a powdered form of BmimCl coated activated carbon was able to uptake Hg0 up to 23 mg/g and 60 mg/g with N2 and CH4 as carrier gas, respectively. A molecular simulation was performed to investigate the molecular level interaction between the Hg0 and the ILs to understand the effect of structural variations of the ILs on Hg0 adsorption. The simulation reveals that the anion part of IL plays a major role in Hg0 adsorption. Based on experimental results, a possible mechanism of Hg-IL interaction was elucidated; the imidazolium cation can form a complex with HgCl2 through the C2 hydrogen. © 2016 Elsevier Ltd. All rights reserved.
date: 2016
publisher: Elsevier Ltd
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84961821991&doi=10.1016%2fj.fuel.2016.03.032&partnerID=40&md5=6705f209e9d9de43a5e0fb11ec8f5c6f
id_number: 10.1016/j.fuel.2016.03.032
full_text_status: none
publication: Fuel
volume: 177
pagerange: 296-303
refereed: TRUE
issn: 00162361
citation:   Abbas, T. and Gonfa, G. and Lethesh, K.C. and Mutalib, M.I.A. and Abai, M.B. and Cheun, K.Y. and Khan, E.  (2016) Mercury capture from natural gas by carbon supported ionic liquids: Synthesis, evaluation and molecular mechanism.  Fuel, 177.  pp. 296-303.  ISSN 00162361