TY  - JOUR
PB  - Elsevier B.V.
SN  - 01677322
EP  - 1144
AV  - none
TI  - Nitrile-functionalized azepanium ionic liquids: Synthesis characterization and thermophysical properties
SP  - 1140
N1  - cited By 7
Y1  - 2016///
VL  - 221
A1  - Lethesh, K.C.
A1  - Shah, S.N.
A1  - Ayodele, O.B.
A1  - Mutalib, M.I.A.
A1  - Uemura, Y.
JF  - Journal of Molecular Liquids
UR  - https://www.scopus.com/inward/record.uri?eid=2-s2.0-84978484221&doi=10.1016%2fj.molliq.2016.06.092&partnerID=40&md5=c60469b987f68993f1d97b8c7206b947
ID  - scholars6855
KW  - Cyanides; Glass transition; Liquids; Melting point; Thermodynamic properties; Thermodynamic stability
KW  -  Azepane; Functionalized; Functionalized ionic liquids; Methanesulfonates; Nitrile functionality; P-toluenesulfonates; Trifluoroacetates; Trifluoromethanesulfonate
KW  -  Ionic liquids
N2  - The synthesis of nitrile-functionalized azepanium ionic liquids such as 1-butyl-1-(2-cyano-ethyl)-azepanium bromide, C4CNAzpBr, 1-butyl-1-(2-cyano-ethyl)azepanium trifluoroacetate, C4CNAzpTFA, 1-butyl-1-(2-cyano-ethyl)-azepanium methanesulfonate C4CNAzpCH3SO3, 1-butyl-1-(2-cyano-ethyl)azepanium trifluoromethanesulfonate C4CNAzpCF3SO3, 1-butyl-1-(2-cyano-ethyl)azepaniummethanesulfateC4CNAzpCH3SO4,1-butyl-1-(2-cyano-ethyl) azepanium p-toluenesulfonate C4CNAzpPTS were performed. The synthesis of ionic liquids was performed in three steps. 1H, 13C and CHNS elemental analysis were used to characterize the synthesized ionic liquids. The thermal stability, melting point and glass transition temperature of the ionic liquids were determined. The nitrile-functionalized ionic liquids showed good thermal stability. © 2016
ER  -