eprintid: 6851
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/68/51
datestamp: 2023-11-09 16:18:39
lastmod: 2023-11-09 16:18:39
status_changed: 2023-11-09 16:07:50
type: article
metadata_visibility: show
creators_name: Gonfa, G.
creators_name: Bustam, M.A.
creators_name: Shariff, A.M.
creators_name: Muhammad, N.
creators_name: Ullah, S.
title: Quantitative structure�activity relationships (QSARs) for estimation of activity coefficient at infinite dilution of water in ionic liquids for natural gas dehydration
ispublished: pub
keywords: Activity coefficients; Dehydration; Driers (materials); Ionic liquids; Liquefied natural gas, Activity coefficient at infinite dilution; Alternative solvents; COSMO-RS; Ionic liquid (ils); Multiple linear regressions; Natural gas dehydration; Quantitative structures; Structural variations, Water absorption
note: cited By 22
abstract: Recently, ionic liquids (ILs) have been considered as alternative solvents to glycol in dehydration of natural gas. However, due to the unlimited structural variations and possible combinations of cations and anions of the ILs, selection of potential ILs for this separation process has been a difficult task. Activity coefficient at infinite dilution is one of the most important thermodynamic properties for preliminary selection of suitable liquid desiccants for water absorption and designing of the natural gas dehydration process. In this paper, COSMO-RS based quantitative structure�property/activity relationship (QSPR/QSAR) models were developed for prediction of activity coefficient of water at infinite dilution in ILs over various temperatures. COSMO-RS based descriptors were generated for 53 ILs (318 data points) at various temperatures. Multiple linear regressions were applied to develop the models. The accuracies of the models were verified by different statistical tests. The model provides a better understanding of the effect of the structural variations of ILs on their affinity for water. © 2016 Taiwan Institute of Chemical Engineers
date: 2016
publisher: Taiwan Institute of Chemical Engineers
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84979528604&doi=10.1016%2fj.jtice.2016.06.027&partnerID=40&md5=00ff5c4e2c2b0b9070b16a6b37e91a4a
id_number: 10.1016/j.jtice.2016.06.027
full_text_status: none
publication: Journal of the Taiwan Institute of Chemical Engineers
volume: 66
pagerange: 222-229
refereed: TRUE
issn: 18761070
citation:   Gonfa, G. and Bustam, M.A. and Shariff, A.M. and Muhammad, N. and Ullah, S.  (2016) Quantitative structure�activity relationships (QSARs) for estimation of activity coefficient at infinite dilution of water in ionic liquids for natural gas dehydration.  Journal of the Taiwan Institute of Chemical Engineers, 66.  pp. 222-229.  ISSN 18761070