TY - JOUR ID - scholars680 KW - Ammonia concentrations; Amoxicillin; Ampicillin; Aqueous solutions; Biological treatment; Cloxacillin; Concentration of; Fenton process; Molar ratio; Operating condition; Optimum operating conditions; Organic nitrogen; Pre-Treatment KW - Ammonia; Biochemical engineering; Biodegradability; Biodegradation; Biological water treatment; Chemical oxygen demand; Concentration (process); Degradation; Mineralogy; Wastewater; Wastewater treatment KW - Antibiotics KW - ammonia; amoxicillin; ampicillin; cloxacillin; dissolved oxygen; hydrogen peroxide; iron; nitrate; organic nitrogen KW - ammonia; antibiotics; aqueous solution; biodegradation; concentration (composition); mineralization; nitrate; optimization; waste treatment KW - aqueous solution; article; biochemical oxygen demand; biodegradability; chemical oxygen demand; controlled study; Fenton reaction; mineralization; oxidation kinetics; pH; process optimization; waste water management KW - Ammonia; Amoxicillin; Ampicillin; Anti-Bacterial Agents; Biodegradation KW - Environmental; Chromatography KW - High Pressure Liquid; Cloxacillin; Hydrogen Peroxide; Hydrogen-Ion Concentration; Indicators and Reagents; Iron; Medical Waste Disposal; Minerals; Oxygen; Solutions; Waste Disposal KW - Fluid; Water N2 - The study examined the effect of operating conditions of the Fenton process on biodegradability improvement and mineralization of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution. In addition, degradation of amoxicillin, ampicillin and cloxacillin under optimum operating conditions were evaluated. The optimum operating conditions for an aqueous solution containing 104, 105 and 103 mg/L amoxicillin, ampicillin, and cloxacillin, respectively were observed to be COD/H2O2/Fe2+ molar ratio 1:3:0.30 and pH 3. Under optimum operating conditions, complete degradation of amoxicillin, ampicillin and cloxacillin occurred in 2 min. In addition, biodegradability improved from �0 to 0.37 in 10 min, and COD and DOC degradation were 81.4 and 54.3, respectively in 60 min. Maximum biodegradability (BOD5/COD ratio) improvement was achieved in 10, 20 and 40 min at antibiotics concentration 100, 250 and 500 mg/L, respectively for each antibiotic in aqueous solution. Increase in nitrate and ammonia concentration were observed due to mineralization of organic nitrogen, concentration of nitrate increased from 0.3 to 10 mg/L and concentration of ammonia increased from 8 to 13 mg/L in 60 min. The study indicated that Fenton process can be used for pretreatment of amoxicillin, ampicillin and cloxacillin wastewater for biological treatment. © 2009 Elsevier B.V. All rights reserved. IS - 2-3 Y1 - 2009/// VL - 170 A1 - Elmolla, E. A1 - Chaudhuri, M. JF - Journal of Hazardous Materials UR - https://www.scopus.com/inward/record.uri?eid=2-s2.0-69049086708&doi=10.1016%2fj.jhazmat.2009.05.013&partnerID=40&md5=64f4e45f597d15750c0afc6071bfb96b AV - none SP - 666 TI - Optimization of Fenton process for treatment of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution N1 - cited By 172 SN - 03043894 EP - 672 ER -