eprintid: 6789
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/67/89
datestamp: 2023-11-09 16:18:35
lastmod: 2023-11-09 16:18:35
status_changed: 2023-11-09 16:07:40
type: article
metadata_visibility: show
creators_name: Ezechi, E.H.
creators_name: Kutty, S.R.B.M.
creators_name: Isa, M.H.
creators_name: Liew, M.S.
title: Application of response surface methodology for the optimization of hexavalent chromium removal using a new low-cost adsorbent
ispublished: pub
keywords: adsorption; chromium; desalination; equilibrium; kinetics; optimization; response analysis; thermodynamics; weed
note: cited By 4
abstract: The adsorption capacity of a novel adsorbent (Ageratum conyzoide leaf powder) was investigated for Cr(VI) removal from aqueous solution. Experiments were designed with the Box�Behnken model of the response surface methodology (RSM). Preliminary experiments were conducted to obtain the optimum range of process variables used for the Box�Behnken model. Three independent variables (pH, initial concentration, and adsorbent mass) were examined. The results show that Cr(VI) removal was more favorable at pH 2. Increase in pH above 2 resulted in negative Cr(VI) removal. Cr(VI) removal increased when adsorbent mass was increased, but decreased with increase in initial concentration. Cr(VI) removal of 92 was obtained at pH 2 and adsorbent mass of 0.3 g. Experiments were successfully optimized by RSM. Kinetics study correlated with the pseudo-second-order kinetic model, whereas equilibrium study was best described by the Langmuir isotherm model with maximum adsorption capacity of 437 mg/g. Thermodynamic parameters indicate a spontaneous, exothermic, and physiosorption process. © 2015 Balaban Desalination Publications. All rights reserved.
date: 2016
publisher: Taylor and Francis Inc.
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84952663833&doi=10.1080%2f19443994.2015.1129506&partnerID=40&md5=3a0792f40d74221bc998baf8875d2a54
id_number: 10.1080/19443994.2015.1129506
full_text_status: none
publication: Desalination and Water Treatment
volume: 57
number: 47
pagerange: 22507-22518
refereed: TRUE
issn: 19443994
citation:   Ezechi, E.H. and Kutty, S.R.B.M. and Isa, M.H. and Liew, M.S.  (2016) Application of response surface methodology for the optimization of hexavalent chromium removal using a new low-cost adsorbent.  Desalination and Water Treatment, 57 (47).  pp. 22507-22518.  ISSN 19443994