eprintid: 6707
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/67/07
datestamp: 2023-11-09 16:18:30
lastmod: 2023-11-09 16:18:30
status_changed: 2023-11-09 16:07:27
type: article
metadata_visibility: show
creators_name: Khan, A.S.
creators_name: Man, Z.
creators_name: Bustam, M.A.
creators_name: Kait, C.F.
creators_name: Ullah, Z.
creators_name: Nasrullah, A.
creators_name: Khan, M.I.
creators_name: Gonfa, G.
creators_name: Ahmad, P.
creators_name: Muhammad, N.
title: Kinetics and thermodynamic parameters of ionic liquid pretreated rubber wood biomass
ispublished: pub
keywords: Activation analysis; Activation energy; Chemical activation; Chemical analysis; Ionic liquids; Kinetics; Liquids; Polymer blends; Rubber; Thermoanalysis; Thermodynamic stability; Thermodynamics; Wood, 1-Butyl-3-methylimidazolium chloride; Chemical compositions; Ionic liquid (ils); Kinetics and thermodynamics; Preexponential factor; Rubber wood; Thermodynamic parameter; Thermodynamics property, Thermogravimetric analysis, Biomass; Chemical Composition; Pretreatment; Pyrolysis; Rubber; Thermal Stability
note: cited By 73
abstract: The impact of ionic liquids (ILs) namely 1-butyl-3-methylimidazolium chloride (BMimCl) and 1-butyl-3-methylimidazolium acetate (BMIMOAc) on rubber wood pyrolysis kinetic and thermodynamic parameters were investigated using thermogravimetric analysis (TGA). The ILs treated and untreated samples were characterized with FT-IR and elemental (CHNS) analyses. The activation energy for untreated and ILs treated rubber wood (RW) were determined using the Flynn-Wall-Ozawa (FWO), Kissinger-Akahira-Sunose (KAS) and Starink methods. The average activation energy calculated using FWO, KAS and Starink methods for untreated rubber wood was 120.15 kJ/mol, 117.10 kJ/mol and 117.60 kJ/mol, BMIMCl treated rubber wood was 87.32 kJ/mol, 77.73 kJ/mol, and 81.16 kJ/mol, while BMIMOAc treated rubber wood was 85.64 kJ/mol, 76.63 kJ/mol, and 80.47 kJ/mol, respectively. Starink method was further used to determine the pre-exponential factor and thermodynamic parameters of untreated and ILs treated samples. The thermo kinetics and thermodynamic parameters indicate that ILs pre-treatment decreases the thermal stability of the rubber wood. From FTIR analysis, it was observed that ILs pre-treatment affected the chemical composition of rubber wood. Elemental analysis showed that ILs treated RW has a higher content of Hydrogen/Carbon ratio because of the separation of lignin and hemicellulose during pre-treatment. It was concluded that ILs pre-treatment provided a potential way to improve the thermal conversion efficiency of rubber wood. © 2016 Elsevier B.V.
date: 2016
publisher: Elsevier B.V.
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84986253602&doi=10.1016%2fj.molliq.2016.09.012&partnerID=40&md5=5b2507aed95cdc18b5bee7bb0470c35e
id_number: 10.1016/j.molliq.2016.09.012
full_text_status: none
publication: Journal of Molecular Liquids
volume: 223
pagerange: 754-762
refereed: TRUE
issn: 01677322
citation:   Khan, A.S. and Man, Z. and Bustam, M.A. and Kait, C.F. and Ullah, Z. and Nasrullah, A. and Khan, M.I. and Gonfa, G. and Ahmad, P. and Muhammad, N.  (2016) Kinetics and thermodynamic parameters of ionic liquid pretreated rubber wood biomass.  Journal of Molecular Liquids, 223.  pp. 754-762.  ISSN 01677322