eprintid: 6660
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/66/60
datestamp: 2023-11-09 16:18:27
lastmod: 2023-11-09 16:18:27
status_changed: 2023-11-09 16:07:20
type: conference_item
metadata_visibility: show
creators_name: Shaharun, M.S.
creators_name: Shaharun, S.
creators_name: Al-Shaibani, A.
title: Effect of zirconia on the physicochemical properties of copper (II) imidazolate frameworks
ispublished: pub
note: cited By 1; Conference of 4th International Conference on Fundamental and Applied Sciences, ICFAS 2016 ; Conference Date: 15 August 2016 Through 17 August 2016; Conference Code:125141
abstract: Copper(II) bis(imidazolate) and copper(II)-zirconia(IV) bimetallic imidazolate were synthesized by metal oxides in aqueous solutions using acid catalyst procedure. The metal imidazolate frameworks were characterized by fourier transform infrared spectra (FTIR), transmission electron microscopy (TEM), ultraviolet-visible spectroscopy (UV-Vis) and N2 adsorption-desorption. The addition of ZrO2 increased the surface area and porosity of the metal organic frameworks. The modification of the copper(II) bis(imidazolate) with addition of ZrO2 enhances the visible light absorbance. The band gap of copper(II)-zirconia(II) bimetallic imidazolate is increased to 2.40 eV with more absorbance in the visible region compared to copper(II) bis(imidazolate). © 2016 Author(s).
date: 2016
publisher: American Institute of Physics Inc.
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85005950839&doi=10.1063%2f1.4968111&partnerID=40&md5=6cc737cb6494a36c194d300677d4428a
id_number: 10.1063/1.4968111
full_text_status: none
publication: AIP Conference Proceedings
volume: 1787
refereed: TRUE
isbn: 9780735414518
issn: 0094243X
citation:   Shaharun, M.S. and Shaharun, S. and Al-Shaibani, A.  (2016) Effect of zirconia on the physicochemical properties of copper (II) imidazolate frameworks.  In: UNSPECIFIED.