@inproceedings{scholars6660, volume = {1787}, note = {cited By 1; Conference of 4th International Conference on Fundamental and Applied Sciences, ICFAS 2016 ; Conference Date: 15 August 2016 Through 17 August 2016; Conference Code:125141}, year = {2016}, doi = {10.1063/1.4968111}, publisher = {American Institute of Physics Inc.}, journal = {AIP Conference Proceedings}, title = {Effect of zirconia on the physicochemical properties of copper (II) imidazolate frameworks}, url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85005950839&doi=10.1063\%2f1.4968111&partnerID=40&md5=6cc737cb6494a36c194d300677d4428a}, abstract = {Copper(II) bis(imidazolate) and copper(II)-zirconia(IV) bimetallic imidazolate were synthesized by metal oxides in aqueous solutions using acid catalyst procedure. The metal imidazolate frameworks were characterized by fourier transform infrared spectra (FTIR), transmission electron microscopy (TEM), ultraviolet-visible spectroscopy (UV-Vis) and N2 adsorption-desorption. The addition of ZrO2 increased the surface area and porosity of the metal organic frameworks. The modification of the copper(II) bis(imidazolate) with addition of ZrO2 enhances the visible light absorbance. The band gap of copper(II)-zirconia(II) bimetallic imidazolate is increased to 2.40 eV with more absorbance in the visible region compared to copper(II) bis(imidazolate). {\^A}{\copyright} 2016 Author(s).}, author = {Shaharun, M. S. and Shaharun, S. and Al-Shaibani, A.}, issn = {0094243X}, isbn = {9780735414518} }