TY  - CONF
AV  - none
KW  - Biomass; Carboxylation; Catalysts; Chemical reactors; Zeolites
KW  -  Biomass pyrolysis; Catalytic pyrolysis; Catalytic upgrading; Deoxygenations; Fixed bed reactor; Pyrolysis oil; Yield; Zeolite structure
KW  -  Catalytic cracking
SP  - 793
TI  - The Role of Zeolite Structure and Acidity in Catalytic Deoxygenation of Biomass Pyrolysis Vapors
ID  - scholars6230
N2  - Catalytic upgrading of paddy husk was performed over 10-MR zeolites (MCM-22, ITQ-2 and ZSM-5) in a drop type fixed-bed reactor. This work investigated the role of structure and acidity of zeolites on pyrolysis-oil yield and degree of deoxygenation. Catalytic pyrolysis experiments were carried out at the catalyst/biomass ratio (0.05-0.5) at temperature of 450°C. The oil yield decreased by using catalyst and this decrease oil yield is attributed to catalytic cracking of bio-oil vapor on the catalyst. The route for deoxygenation of pyrolysis vapors was identified to be dehydration, decarboxylation and decarboxylation. ITQ-2 showed high degree of deoxygenation as compare to MCM-22 which is due to more accessible external active sites of ITQ-2. The organics yield in pyrolysis oil was highest with ZSM-5 in comparison with other zeolites. © 2015 The Authors. Published by Elsevier Ltd.
N1  - cited By 37; Conference of 7th International Conference on Applied Energy, ICAE 2015 ; Conference Date: 28 March 2015 Through 31 March 2015; Conference Code:114863
SN  - 18766102
PB  - Elsevier Ltd
Y1  - 2015///
VL  - 75
EP  - 800
UR  - https://www.scopus.com/inward/record.uri?eid=2-s2.0-84947067761&doi=10.1016%2fj.egypro.2015.07.126&partnerID=40&md5=fe9b50c0ca2cd75493872bab760620a5
A1  - Naqvi, S.R.
A1  - Uemura, Y.
A1  - Yusup, S.
A1  - Sugiur, Y.
A1  - Nishiyama, N.
A1  - Naqvi, M.
ER  -