eprintid: 5997
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/59/97
datestamp: 2023-11-09 16:17:44
lastmod: 2023-11-09 16:17:44
status_changed: 2023-11-09 16:04:30
type: article
metadata_visibility: show
creators_name: Sundramoorthy, J.D.
creators_name: Sabil, K.M.
creators_name: Lal, B.
creators_name: Hammonds, P.
title: Catastrophic crystal growth of clathrate hydrate with a simulated natural gas system during a pipeline shut-in condition
ispublished: pub
keywords: Gases; Hydration; Mass transfer; Methane; Natural gas; Phase interfaces, Clathrate hydrate; Crystal formation; Hydrate structures; Isochoric conditions; Natural gas systems; Nucleation and growth; Transport mechanism; Water interface, Gas hydrates
note: cited By 25
abstract: This paper presents a significant finding where capillary-aided catastrophic gas hydrate growth is observed under a shut-in condition (static fluid) for an uninhibited system. With the use of a newly designed apparatus, consisting of six units of identical rocking cell, nucleation and growth are observed. All experiments are conducted under isochoric conditions using 11.0 K subcooling (�Tsub) as a driving force. A simulated natural gas mixture of 90.0 mol  methane + 10.0 mol  propane is used as a gas phase. The liquid phase used is 3 (Na+, Cl-) brine. The observations of the capillary-aided mass-transport mechanism for a catastrophic gas hydrate growth are presented in this work. Our observations show hydrate crystal formation at a brine wetted area close to the brine/gas interface initiates capillary-aided catastrophic hydrate growth. Moreover, no mass transfer restriction of brine toward catastrophic gas hydrate growth is observed. Furthermore, our results show the denser (less porous appearance) hydrate structures are continuously displaced from the hydrate-water interface (hydrate growth side). This displacement allowed new hydrate crystals to be formed uninterruptedly until the exhaustion of water in the cells. On the basis of macroscopic observations, the capillary-aided mass-transport mechanism for a catastrophic gas hydrate growth is presented. © 2015 American Chemical Society.
date: 2015
publisher: American Chemical Society
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84929180209&doi=10.1021%2fcg501626h&partnerID=40&md5=05d6199848b9b6071ec6fad39a25d144
id_number: 10.1021/cg501626h
full_text_status: none
publication: Crystal Growth and Design
volume: 15
number: 3
pagerange: 1233-1241
refereed: TRUE
issn: 15287483
citation:   Sundramoorthy, J.D. and Sabil, K.M. and Lal, B. and Hammonds, P.  (2015) Catastrophic crystal growth of clathrate hydrate with a simulated natural gas system during a pipeline shut-in condition.  Crystal Growth and Design, 15 (3).  pp. 1233-1241.  ISSN 15287483