TY - JOUR AV - none N1 - cited By 29 TI - Dual template route for the synthesis of hierarchical porous boron nitride SP - 3806 PB - Elsevier Ltd SN - 02728842 EP - 3813 IS - 3 N2 - Here, a facile dual templates method for the synthesis of hierarchical porous boron nitride (HPBN) powders is reported. For this purpose, ammonia borane (AB) and polystyrene latex/cetyltrimethyl ammonium bromide (CTAB) were used as BN precursor and inorganic templates, respectively. The as-synthesized material was pyrolyzed at 1150 °C in ammonia atmosphere resulting in the formation of white BN powder. The typical N2 sorption analysis demonstrated formation of porous BN with presence of macro/meso and micropores. Transmission electron microscope (TEM) observations revealed the existence of rather uniform macropores with 55-60 nm in diameter, as well as wormlike mesopores and micropores extended between macropores walls. X-ray diffraction (XRD) and high resolution TEM (HRTEM) analyses displayed the formation of turbostratic-BN with atomic layer distance of 0.37 nm. HPBN powders showed fast adsorption rate of methylene blue (MB) solution and high adsorption capacity of 263.1 mg g-1 for MB at room temperature. © 2014 Elsevier Ltd and Techna Group S.r.l. ID - scholars5985 KW - Ammonia; Aromatic compounds; Boron nitride; Microporosity; Nitrides; Polystyrenes; Powders; Transmission electron microscopy KW - Ammonia atmosphere; CTAB; Hierarchical porous; High adsorption capacity; High-resolution TEM; Inorganic templates; Polystyrene latexes; Synthesized materials KW - III-V semiconductors Y1 - 2015/// A1 - Maleki, M. A1 - Beitollahi, A. A1 - Javadpour, J. A1 - Yahya, N. JF - Ceramics International UR - https://www.scopus.com/inward/record.uri?eid=2-s2.0-84921830424&doi=10.1016%2fj.ceramint.2014.11.056&partnerID=40&md5=f5358d5de8f96ce553cc64e779c0df95 VL - 41 ER -