@article{scholars5985, publisher = {Elsevier Ltd}, journal = {Ceramics International}, pages = {3806--3813}, year = {2015}, title = {Dual template route for the synthesis of hierarchical porous boron nitride}, number = {3}, volume = {41}, note = {cited By 29}, doi = {10.1016/j.ceramint.2014.11.056}, abstract = {Here, a facile dual templates method for the synthesis of hierarchical porous boron nitride (HPBN) powders is reported. For this purpose, ammonia borane (AB) and polystyrene latex/cetyltrimethyl ammonium bromide (CTAB) were used as BN precursor and inorganic templates, respectively. The as-synthesized material was pyrolyzed at 1150 {\^A}oC in ammonia atmosphere resulting in the formation of white BN powder. The typical N2 sorption analysis demonstrated formation of porous BN with presence of macro/meso and micropores. Transmission electron microscope (TEM) observations revealed the existence of rather uniform macropores with 55-60 nm in diameter, as well as wormlike mesopores and micropores extended between macropores walls. X-ray diffraction (XRD) and high resolution TEM (HRTEM) analyses displayed the formation of turbostratic-BN with atomic layer distance of 0.37 nm. HPBN powders showed fast adsorption rate of methylene blue (MB) solution and high adsorption capacity of 263.1 mg g-1 for MB at room temperature. {\^A}{\copyright} 2014 Elsevier Ltd and Techna Group S.r.l.}, url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-84921830424&doi=10.1016\%2fj.ceramint.2014.11.056&partnerID=40&md5=f5358d5de8f96ce553cc64e779c0df95}, keywords = {Ammonia; Aromatic compounds; Boron nitride; Microporosity; Nitrides; Polystyrenes; Powders; Transmission electron microscopy, Ammonia atmosphere; CTAB; Hierarchical porous; High adsorption capacity; High-resolution TEM; Inorganic templates; Polystyrene latexes; Synthesized materials, III-V semiconductors}, author = {Maleki, M. and Beitollahi, A. and Javadpour, J. and Yahya, N.}, issn = {02728842} }