eprintid: 5951
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/59/51
datestamp: 2023-11-09 16:17:42
lastmod: 2023-11-09 16:17:42
status_changed: 2023-11-09 16:04:20
type: article
metadata_visibility: show
creators_name: Ayodele, O.B.
creators_name: Farouk, H.U.
creators_name: Mohammed, J.
creators_name: Uemura, Y.
creators_name: Daud, W.M.A.W.
title: Hydrodeoxygenation of oleic acid into n- and iso-paraffin biofuel using zeolite supported fluoro-oxalate modified molybdenum catalyst: Kinetics study
ispublished: pub
keywords: Activation energy; Catalysts; Fluorine compounds; Isomerization; Kinetics; Molybdenum; Oleic acid; Oxalic acid; Reusability; Zeolites, Dissolution methods; Experimental conditions; Functionalized; Hydrodeoxygenation; Kinetic study; Kinetics studies; Molybdenum catalyst; Morphological properties, Biofuels
note: cited By 30
abstract: The activity of zeolite supported fluoride-ion functionalized molybdenum-oxalate catalyst (FMoOx/Zeol) and its kinetic study on the hydrodeoxygenation (HDO) of oleic acid (OA) is presented in this report. The FMoOx/Zeol was synthesized via simple dissolution method and characterized. The results revealed formation of highly reactive octahedral Mo species with enhanced textural and morphological properties. The FMoOx/Zeol activity on the HDO of OA at the best observed experimental conditions of 360°C, 30mg FMoOx/Zeol and 20 bar produces 64 n-C18H38 and 30 iso-C18H38 in 60min. The acidity of FMoOx/Zeol was responsible for the production of the iso-C18H38. The kinetic data showed that sequential hydrogenation of OA into stearic acid (SA) was faster than the HDO of SA into biofuel with activation energies of 98.7 and 130.3kJ/mol, respectively. The reusability studies showed consistency after three consecutive runs amounting to 180min reaction time. The results are encouraging towards industrial application. © 2015 Taiwan Institute of Chemical Engineers.
date: 2015
publisher: Taiwan Institute of Chemical Engineers
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84930577184&doi=10.1016%2fj.jtice.2014.12.014&partnerID=40&md5=a31034d887ff0c91b57cdf56d73f7598
id_number: 10.1016/j.jtice.2014.12.014
full_text_status: none
publication: Journal of the Taiwan Institute of Chemical Engineers
volume: 50
pagerange: 142-152
refereed: TRUE
issn: 18761070
citation:   Ayodele, O.B. and Farouk, H.U. and Mohammed, J. and Uemura, Y. and Daud, W.M.A.W.  (2015) Hydrodeoxygenation of oleic acid into n- and iso-paraffin biofuel using zeolite supported fluoro-oxalate modified molybdenum catalyst: Kinetics study.  Journal of the Taiwan Institute of Chemical Engineers, 50.  pp. 142-152.  ISSN 18761070