eprintid: 5807
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/58/07
datestamp: 2023-11-09 16:17:33
lastmod: 2023-11-09 16:17:33
status_changed: 2023-11-09 16:03:56
type: article
metadata_visibility: show
creators_name: Khan, Z.
creators_name: Inayat, A.
creators_name: Yusup, S.
creators_name: Ahmad, M.M.
title: Kinetic parameters determination using optimization approach in integrated catalytic adsorption steam gasification for hydrogen production
ispublished: pub
keywords: Abstracting; Biomass; Carbon dioxide; Chemical shift; Gasification; Hydrogen production; Kinetic parameters; Optimization; Steam; Temperature; Water gas shift, CO2 adsorption; Effect of temperature; Optimization approach; Palm kernel shells; Parameters determination; Steam gasification; Temperature range; Water gas shift (WGS) reaction, Gas adsorption
note: cited By 8
abstract: Abstract Integrated catalytic adsorption (ICA) gasification provides an efficient mean to produce hydrogen rich gas. This article presents the prospect of ICA steam gasification of palm kernel shell. The effect of temperature, steam to biomass ratio and adsorbent to biomass are investigated for H2, CO, CO2 and CH4 composition to determine kinetic parameters by minimizing the error between experimental and modelling results. Based on the evaluated kinetic parameters, the model predicts the product gas composition for the effect of temperature, steam to biomass ratio and adsorbent to biomass ratio. A significant fitting of model predicted values to the experimental results is achieved. Furthermore, it is also found that the water gas shift reaction is non-spontaneous and far away from the equilibrium at a temperature range of 600°C-675°C which may be due to strong CO2 adsorption reaction. © 2015 Hydrogen Energy Publications, LLC.
date: 2015
publisher: Elsevier Ltd
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84937728789&doi=10.1016%2fj.ijhydene.2015.05.069&partnerID=40&md5=194c92c7810ef986875b9d0e5011376d
id_number: 10.1016/j.ijhydene.2015.05.069
full_text_status: none
publication: International Journal of Hydrogen Energy
volume: 40
number: 29
pagerange: 8824-8832
refereed: TRUE
issn: 03603199
citation:   Khan, Z. and Inayat, A. and Yusup, S. and Ahmad, M.M.  (2015) Kinetic parameters determination using optimization approach in integrated catalytic adsorption steam gasification for hydrogen production.  International Journal of Hydrogen Energy, 40 (29).  pp. 8824-8832.  ISSN 03603199