TY  - JOUR
KW  - Abstracting; Biomass; Carbon dioxide; Chemical shift; Gasification; Hydrogen production; Kinetic parameters; Optimization; Steam; Temperature; Water gas shift
KW  -  CO2 adsorption; Effect of temperature; Optimization approach; Palm kernel shells; Parameters determination; Steam gasification; Temperature range; Water gas shift (WGS) reaction
KW  -  Gas adsorption
IS  - 29
TI  - Kinetic parameters determination using optimization approach in integrated catalytic adsorption steam gasification for hydrogen production
N2  - Abstract Integrated catalytic adsorption (ICA) gasification provides an efficient mean to produce hydrogen rich gas. This article presents the prospect of ICA steam gasification of palm kernel shell. The effect of temperature, steam to biomass ratio and adsorbent to biomass are investigated for H2, CO, CO2 and CH4 composition to determine kinetic parameters by minimizing the error between experimental and modelling results. Based on the evaluated kinetic parameters, the model predicts the product gas composition for the effect of temperature, steam to biomass ratio and adsorbent to biomass ratio. A significant fitting of model predicted values to the experimental results is achieved. Furthermore, it is also found that the water gas shift reaction is non-spontaneous and far away from the equilibrium at a temperature range of 600°C-675°C which may be due to strong CO2 adsorption reaction. © 2015 Hydrogen Energy Publications, LLC.
SN  - 03603199
EP  - 8832
ID  - scholars5807
AV  - none
SP  - 8824
PB  - Elsevier Ltd
Y1  - 2015///
UR  - https://www.scopus.com/inward/record.uri?eid=2-s2.0-84937728789&doi=10.1016%2fj.ijhydene.2015.05.069&partnerID=40&md5=194c92c7810ef986875b9d0e5011376d
N1  - cited By 8
A1  - Khan, Z.
A1  - Inayat, A.
A1  - Yusup, S.
A1  - Ahmad, M.M.
JF  - International Journal of Hydrogen Energy
VL  - 40
ER  -