%0 Journal Article
%@ 18755100
%A Nasir, Q.
%A Sabil, K.M.
%A Lau, K.K.
%D 2015
%F scholars:5639
%I Elsevier B.V.
%J Journal of Natural Gas Science and Engineering
%K Binary mixtures; Equations of state; Isotherms; Liquefied natural gas; Liquid methane; Natural gas substitutes; Sapphire; Temperature; Van der Waals forces; Vapor pressure, Binary interaction parameter; GERG-EOS; Isothermal vapor-liquid equilibrium; Peng-Robinson equation of state; Synthetic natural gas; Temperature and pressures; Temperature dependent; VTPR-EOS, Carbon dioxide
%P 158-167
%R 10.1016/j.jngse.2015.08.045
%T Measurement of isothermal (vapor+liquid) equilibria, (VLE) for binary (CH4+CO2) from T=(240.35 to 293.15) K and CO2 rich synthetic natural gas systems from T=(248.15 to 279.15) K
%U https://khub.utp.edu.my/scholars/5639/
%V 27
%X Isothermal vapor-liquid equilibrium (VLE) data for methane (CH4) + carbon dioxide (CO2) binary system at temperature range of (240.35-293.15) K and synthetic carbon dioxide rich natural gas mixtures at temperature and pressure range of (248.15-279.15) K and (2.81-9.05) MPa were measured in sapphire type equilibrium cell apparatus. Thermodynamic modeling of experimental data was carried out with GERG2008-equation of state (EOS) and volume-translated Peng-Robinson equation of state (VTPR-EOS) using van der Waals (vdw1) mixing rule. For CH4 + CO2 system, the temperature dependent binary interaction parameters (kij) were tuned to measured VLE data, whereas, between CO2 with other hydrocarbons the value of kij=0 was assumed. Comparison between measured and prediction shows excellent agreement with overall lower deviations were obtained. © 2015 Elsevier B.V.
%Z cited By 25