%0 Journal Article %@ 00319104 %A Perumalsamy, M. %A Murugesan, T. %D 2014 %F scholars:5485 %J Physics and Chemistry of Liquids %K Aqueous two phase system; Electrostatic potentials; Liquid liquid equilibrium; Long range interactions; Polyethylene glycol (PEG); Potential difference; Satisfactory predictions, Phase equilibria; Sodium, Tools %N 1 %P 26-36 %R 10.1080/00319104.2013.795857 %T Liquid-liquid equilibrium of aqueous two-phase system (PEG 2000-Sodium Citrate-Water) using potential difference as a key tool %U https://khub.utp.edu.my/scholars/5485/ %V 52 %X The present work involves an attempt to demonstrate the application of potential difference, existing across the interface of the aqueous two-phase system (ATPS), as a tool for the prediction of the phase equilibrium. The contribution due to long-range interaction for the potential difference and its variation with the composition is studied for the polyethylene glycol (PEG) 2000-Sodium Citrate-Water-based ATPS (Merck, Germany). The developed correlation for the potential difference with concentration shows a satisfactory prediction of the phase equilibrium for the present system. © 2014 Taylor and Francis Group, LLC. %Z cited By 3