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Cu-Fe/TiO2 photocatalyst for deep desulfurization process
A series of Cu-Fe/TiO2 photocatalysts were prepared and calcined at 400°C and 500°C for 1 h. The photocatalysts were characterized using diffuse reflectance spectroscopy (DR-UV-Vis), X-ray diffraction (XRD) and field-emission scanning electron microscopy (FESEM). The performance for sulfur removal was carried out using model oil containing 100 ppm S (from dibenzothiophene). The highly dispersed Cu-Fe/TiO2 photocatalyst displayed mainly spherical shaped particles. The best performing photocatalyst was 0.8wt Cu-Fe loading and calcined at 400°C (0.8wt400) giving 18 sulfur removal. The band gap for 0.8wt400 was lowered to 2.96 eV compared to 3.21 eV for TiO2 © (2014) Trans Tech Publications, Switzerland.
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