%I Taylor and Francis Inc.
%P 647-654
%J Journal of Dispersion Science and Technology
%T Synthesis of a New CO2 Philic Surfactant for Enhanced Oil Recovery Applications
%V 35
%R 10.1080/01932691.2013.803253
%K Activation energy; Enhanced recovery; Enzyme kinetics; Esterification; Maleic anhydride; Reaction kinetics; Surface active agents; Surface tension; Enzyme kinetics; Surface active agents, Diesters; Enhanced oil recovery; EOR; Esterification reactions; First order reactions; Fumarates, Carbon dioxide; Surface tension
%L scholars5393
%O cited By 20
%X The synthesis of CO2 philic surfactant using maleic anhydride and 4-tert-butylbenzyl alcohol is reported. We reacted maleic anhydride with 4-tert-butylbenzyl alcohol to form bis(4-(tert-butyl)benzyl) fumarate and sulfonated the produced diester. The esterification reaction was optimized for a maximum yield of 98 of bis(4-(tert-butyl)benzyl) fumarate. First-order reaction kinetics with respect to acid was observed. The activation energy was found to be 55.62 kJ/mol. The sulfonated product of diester was obtained by the sulfonation reaction and the yield of 82 of surfactant was achieved. The in-house developed surfactant effectively lowered down the IFT between CO2/brine to 4.2 mN/m. This surfactant is targeted for CO2-EOR applications. © 2014 Copyright Taylor & Francis Group, LLC.
%N 5
%A M. Sagir
%A I.M. Tan
%A M. Mushtaq
%A L. Ismail
%A M. Nadeem
%A M.R. Azam
%D 2014