eprintid: 5126 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/00/51/26 datestamp: 2023-11-09 16:16:50 lastmod: 2023-11-09 16:16:50 status_changed: 2023-11-09 16:00:40 type: article metadata_visibility: show creators_name: Sagir, M. creators_name: Tan, I.M. creators_name: Mushtaq, M. creators_name: Nadeem, M. title: CO2 Mobility and CO2/Brine Interfacial Tension Reduction by Using a New Surfactant for EOR Applications ispublished: pub keywords: Activation energy; Enhanced recovery; Enzyme kinetics; Esterification; Esters; Maleic anhydride; Reaction kinetics; Sulfonation; Surface active agents; Surface tension; Synthesis (chemical), Diesters; Enhanced oil recovery; EOR; Esterification reactions; Mobility control; Silica sulfuric acids; Sodium bisulfite, Carbon dioxide note: cited By 16 abstract: The synthesis and use in enhanced oil recovery applications of a novel CO2-philic surfactant derived from maleic anhydride and 2-butyl-1-octanol is reported. The synthesis involved the esterification of maleic anhydride to produce diester followed by sulfonation of the esterified product. The esterification reaction parameters were optimized for the maximum yield of 98.4. By employing a silica sulfuric acid catalyst, the reaction kinetics of esterification were also investigated. The activation energy was found to be 45.58 kJ/mol. The sulfonation reaction of the esterified product was performed by using sodium bisulfite, and a yield of 82 of surfactant was achieved. The synthesized surfactant lowered the interfacial tension between CO2/brine to 3.1 mN/m and effectively reduced the CO2 mobility. This surfactant has a great potential to be used for CO2 mobility control for CO2-EOR applications. © 2014 Copyright Taylor & Francis Group, LLC. date: 2014 publisher: Taylor and Francis Inc. official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84904536157&doi=10.1080%2f01932691.2013.859087&partnerID=40&md5=2c8b321a7c964f5e2b3811aa9ed979f0 id_number: 10.1080/01932691.2013.859087 full_text_status: none publication: Journal of Dispersion Science and Technology volume: 35 number: 11 pagerange: 1512-1519 refereed: TRUE issn: 01932691 citation: Sagir, M. and Tan, I.M. and Mushtaq, M. and Nadeem, M. (2014) CO2 Mobility and CO2/Brine Interfacial Tension Reduction by Using a New Surfactant for EOR Applications. Journal of Dispersion Science and Technology, 35 (11). pp. 1512-1519. ISSN 01932691