relation: https://khub.utp.edu.my/scholars/4786/ title: Effect of the solvent molar ratios on the synthesis of zeolitic imidazolate framework 8 (ZIF-8) and its performance in CO2 adsorption creator: Lai, L.S. creator: Yin Fong, Y. creator: Che Ani, N. creator: Kok Keong, L. creator: Azmi, M.S. description: In this research work, ZIF-8 was synthesized at room temperature using different synthesis solutions contained different molar ratios of methanol to zinc nitrate. The properties of the resultant particles were characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM) and thermal gravimetric analysis (TGA). The basicity of the ZIF-8 samples was measured using temperature programmed desorption (TPD). Results showed that ZIF-8 samples synthesized in the present work were thermally stable up to 700 ºC. ZIF-8 synthesized using synthesis solution contained lowest molar ratio of methanol to zinc nitrate of 86.7 possessed highest crystallinity and largest average particles sizes of ~250 nm. Besides, this sample also demonstrated highest CO2 uptake rate due to the presence of highest amount of basic site of 0.70 mmol/g among the ZIF-8 samples. © 2014 Trans Tech Publications, Switzerland. publisher: Trans Tech Publications Ltd date: 2014 type: Article type: PeerReviewed identifier: Lai, L.S. and Yin Fong, Y. and Che Ani, N. and Kok Keong, L. and Azmi, M.S. (2014) Effect of the solvent molar ratios on the synthesis of zeolitic imidazolate framework 8 (ZIF-8) and its performance in CO2 adsorption. Applied Mechanics and Materials, 625. pp. 69-72. ISSN 16609336 relation: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84914127167&doi=10.4028%2fwww.scientific.net%2fAMM.625.69&partnerID=40&md5=747cc708c877ec5e05778f28ea499166 relation: 10.4028/www.scientific.net/AMM.625.69 identifier: 10.4028/www.scientific.net/AMM.625.69