eprintid: 4709 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/00/47/09 datestamp: 2023-11-09 16:16:25 lastmod: 2023-11-09 16:16:25 status_changed: 2023-11-09 15:59:12 type: article metadata_visibility: show creators_name: Azizan, M.T. creators_name: Hellgardt, K. creators_name: Chadwick, D. title: Thermodynamic analysis of autothermal reforming of oxygenated hydrocarbons at thermoneutral condition for hydrogen production ispublished: pub keywords: Atoms; Ethanol; Ethylene; Ethylene glycol; Glycerol; Hydrocarbons; Molecules; Oxygen; Polyols; Propylene; Thermoanalysis; Thermodynamic properties; Thermodynamics, Autothermal reforming; Hydrogen atoms; Hydrogen selectivity; Oxygen atom; Oxygenated hydrocarbon; Propylene glycols; Thermo dynamic analysis; Thermoneutral, Hydrogen production note: cited By 5; Conference of 3rd International Conference on Process Engineering and Advanced Materials, ICPEAM 2014 ; Conference Date: 3 June 2014 Through 5 June 2014; Conference Code:114811 abstract: The thermodynamic analysis of autothermal reforming of homologue series consisted of ethanol, ethylene glycol, propylene glycol and glycerol representing oxygenated hydrocarbons were studied. The main investigation was to compare the effect of thermoneutral condition where no external air/oxygen supplied for the reaction to sustain and controlled amount of air/oxygen supplied. It was found that the higher number of oxygen atoms in these homologues molecule, the higher tendency of the reaction to be sustained at the desired temperature, and thus it only requires lesser amount of air for heating. The hydrogen selectivity however depends on the ratio of hydrogen atoms with respect to the oxygen atoms in each molecule. The presence of air however, though providing extra heating to the reactor, is offset by a lower hydrogen production. © 2014 Trans Tech Publications, Switzerland. date: 2014 publisher: Trans Tech Publications Ltd official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84914160573&doi=10.4028%2fwww.scientific.net%2fAMM.625.730&partnerID=40&md5=81dd8a79a86374967535330354ba5970 id_number: 10.4028/www.scientific.net/AMM.625.730 full_text_status: none publication: Applied Mechanics and Materials volume: 625 pagerange: 730-733 refereed: TRUE isbn: 9783038351818 issn: 16609336 citation: Azizan, M.T. and Hellgardt, K. and Chadwick, D. (2014) Thermodynamic analysis of autothermal reforming of oxygenated hydrocarbons at thermoneutral condition for hydrogen production. Applied Mechanics and Materials, 625. pp. 730-733. ISSN 16609336