eprintid: 4443 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/00/44/43 datestamp: 2023-11-09 16:16:07 lastmod: 2023-11-09 16:16:07 status_changed: 2023-11-09 15:58:27 type: article metadata_visibility: show creators_name: Tasfy, S.F.H. creators_name: Mohd Zabidi, N.A. creators_name: Subbarao, D. title: Effects of Cu and K promoters on the catalytic performance of ironbased nanocatalyst for Fischer-Tropsch synthesis ispublished: pub keywords: Catalytic performance; CO conversion; Heavy hydrocarbons; Impregnation methods; Nano-catalyst; Potassium promoters; Reactant ratios; Space velocities, Atmospheric pressure; Hydrocarbons; Nanoscience, Fischer-Tropsch synthesis note: cited By 1; Conference of 2013 International Conference on Nanoscience and Nanotechnology, NANO-SciTech 2013 ; Conference Date: 1 March 2013 Through 4 March 2013; Conference Code:101772 abstract: Iron-based nanocatalyst was prepared via impregnation method on SiO2 support. The effects of promoters, namely, K and Cu, on the physical properties and catalytic performance in FTS have been investigated. The FTS performance of the synthesized nanocatalysts was examined in a fixed-bed microreactor at temperature of 523K, atmospheric pressure, 1.5 reactant ratio (H2/CO) and space velocity of 3L/g-cat.h. In FTS reaction, Cu promoter resulted in a lower CO conversion and C5+ hydrocarbons selectivity but higher selectivity to the lighter hydrocarbons (C1- C4) compared to those obtained using the K promoter. Higher CO conversion (28.9) and C5+ hydrocarbons selectivity (54.4) were obtained using K as a promoter compared to that of Cu promoter. However, the K-promoted nanocatalyst resulted in a lower CO conversion but higher selectivity of the heavy hydrocarbons (C5+) compared to those obtained using the un-promoted nanocatalyst. © (2014) Trans Tech Publications, Switzerland. date: 2014 official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84891592392&doi=10.4028%2fwww.scientific.net%2fAMR.832.15&partnerID=40&md5=2be5b335cd37ed53f22a8ef38ad10c57 id_number: 10.4028/www.scientific.net/AMR.832.15 full_text_status: none publication: Advanced Materials Research volume: 832 place_of_pub: Shah Alam, Selangor pagerange: 15-20 refereed: TRUE isbn: 9783037859131 issn: 10226680 citation: Tasfy, S.F.H. and Mohd Zabidi, N.A. and Subbarao, D. (2014) Effects of Cu and K promoters on the catalytic performance of ironbased nanocatalyst for Fischer-Tropsch synthesis. Advanced Materials Research, 832. pp. 15-20. ISSN 10226680