eprintid: 4047
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/40/47
datestamp: 2023-11-09 15:52:19
lastmod: 2023-11-09 15:52:19
status_changed: 2023-11-09 15:48:12
type: article
metadata_visibility: show
creators_name: Yousaf, M.
creators_name: Pervaiz, M.
creators_name: Zahoor, A.F.
creators_name: Hussain, A.I.
creators_name: Khosa, M.K.K.
creators_name: Ashraf, S.
creators_name: Sagir, M.
creators_name: Ashar-Uz-Zaman, 
creators_name: Shehzad, K.
title: Synthesis, characterization and biological studies of bis-μ-2,2'- ethane-1,3-diylbis(nitrilomethylidyne)diphenolatodicopper(II) Using Triple Component Solvent System
ispublished: pub
note: cited By 10
abstract: The bis-μ-2,2'-ethane-1,3-diyl-bis(nitrilomethylidyne)diphenolato dicopper(II) with the molecular formula Cu2(C16H 14N2O2)2 shows the dimeric complex. Distorted square pyramidal geometry is formed in the community of CuII distinct by the two nitrogen atoms and two oxygen atoms of the N,N'-bis-(salicylidene)- 1,2-ethylene-diamine (ligand) and one oxygen atom commencing both ligand performing as bridge between two ligand molecules, which are wraped in parallel path among each other. In toluene the tilted complex showed crystalline structure but to acquire more apparent X-ray crystallographic data a combination of three solvent (toluene, ethanol, ethyl acetate) was used. The synthesized ligand was analyzed and characterized by mass spectrometry, Fourier transform infrared spectroscopy, nuclear magnetic resonance spectroscopy while the titled compound was characterized by X-ray crystallography and FTIR. The complex and ligand were also engaged for antifungal and antibacterial activities against fungal species A. flavus, A. alternate and A. niger and against bacterial species Staphylococcus aureus, Escheria coli and Bacillus subbtilis. The results of these activities showed that the metal complex has extra antibacterial and antifungal actions than the precursor (ligand) against different culture media.
date: 2013
publisher: Chemical Publishing Co.
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84871223213&doi=10.14233%2fajchem.2013.13412&partnerID=40&md5=00a97cb6b6d3547dfdf7532ae6e0013f
id_number: 10.14233/ajchem.2013.13412
full_text_status: none
publication: Asian Journal of Chemistry
volume: 25
number: 1
pagerange: 521-524
refereed: TRUE
issn: 09707077
citation:   Yousaf, M. and Pervaiz, M. and Zahoor, A.F. and Hussain, A.I. and Khosa, M.K.K. and Ashraf, S. and Sagir, M. and Ashar-Uz-Zaman and Shehzad, K.  (2013) Synthesis, characterization and biological studies of bis-μ-2,2'- ethane-1,3-diylbis(nitrilomethylidyne)diphenolatodicopper(II) Using Triple Component Solvent System.  Asian Journal of Chemistry, 25 (1).  pp. 521-524.  ISSN 09707077