%K Co-precipitated; Coprecipitation method; Coral-like; Field emission scanning electron microscopy; FTIR; Hydrotalcite-like compound; Hydrotalcites; Mixed oxide; Nano-sized particles; Nano-structured; Nitrogen adsorption-desorption techniques; Plate-like morphology; Powder X ray diffraction; Structure and morphology; Synthesized materials; Templating agents, Calcination; Cobalt; Coprecipitation; Fast Fourier transforms; Fourier transform infrared spectroscopy; High resolution transmission electron microscopy; Morphology; Nanostructures; Nickel; X ray diffraction, Aluminum
%X Nano-structured hydrotalcite-like compounds that contain nickel, cobalt and aluminum have been synthesized by conventional coprecipitation method without using any surfactants or templating agents. The structure and morphology of the coprecipitated nano hydrotalcites and its derived mixed oxides were characterized by powder X-ray diffraction (XRD), Fourier-transformed Infrared (FTIR) spectroscopy, field-emission scanning electron microscopy (FESEM), high resolution transmission electron microscopy (HRTEM), and nitrogen adsorption-desorption techniques. The results show that the synthesized materials exhibited micro-meso-pore networks. The cobalt-rich calcined hydrotalcites are generally amorphous, having a coral-like morphology whereas nickel-rich hydrotalcites show hexagonal plate-like morphology. The presence of nickel in mixed oxides catalyzed the reduction of Co-Al-O spinels. The Fast Fourier Transform (FFT) analysis of HRTEM revealed the inter planner distances of the crystal of hydrotalcite. © (2013) Trans Tech Publications, Switzerland.
%A M.A. Salam
%A Y. Lwin
%A S. Sufian
%L scholars3755
%P 173-177
%J Advanced Materials Research
%R 10.4028/www.scientific.net/AMR.626.173
%C Penang
%D 2013
%O cited By 10; Conference of 2012 International Conference on Advanced Materials Engineering and Technology, ICAMET 2012 ; Conference Date: 28 November 2012 Through 30 November 2012; Conference Code:95061
%T Synthesis of nano-structured Ni-Co-Al hydrotalcites and derived mixed oxides
%V 626